Chapter 4: Problem 24
The ideal gas law states that the volume \(V\) that a gas occupies is directly proportional to the product of the number \(n\) of moles of gas and the temperature \(T\) (in \(\mathrm{K}\) ) and is inversely proportional to the pressure \(P\) (in atmospheres). (a) Express \(V\) in terms of \(n, T, P\), and a constant of proportionality \(k\). (b) What is the effect on the volume if the number of moles is doubled and both the temperature and the pressure are reduced by a factor of one-half?
Short Answer
Step by step solution
Understand the Ideal Gas Law
Express Volume \(V\) with Proportionality
Analyze Changes to Variables
Substitute and Simplify
Conclude
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Volume in the Ideal Gas Law
Understanding Proportionality in Gases
- Direct Proportionality: Volume is directly proportional to the product of moles \( n \) and temperature \( T \). This means that if you increase the number of moles or the temperature, the volume will also increase.
- Inverse Proportionality: Volume is inversely proportional to pressure \( P \), meaning that if pressure increases, the volume decreases if all other factors are constant.
How Temperature Affects Gas Volume
- As temperature increases, for a constant amount of gas and pressure, the volume will increase.
- If temperature decreases, the volume decreases assuming the amount of gas and pressure remain constant.
Pressure and Its Impact on Gas Volume
- Increasing the pressure, while keeping moles and temperature constant, leads to a decrease in volume.
- Conversely, decreasing the pressure allows the volume to expand if moles and temperature are unchanged.
Role of Moles in Gas Volume
- Increasing the moles (amount of gas) increases the volume, assuming temperature and pressure are unchanged.
- Decreasing the moles will lead to a decrease in volume, given constant temperature and pressure.