Chapter 9: Problem 114
Which statement(s) is/are correct regarding copper sulphate? (a) It gives CuO on strorng heating in air. (b) Ir rcacrs wirh KI ro give brown colouration. (c) Ir reacts wirh \(\mathrm{KCl}\) ?o give \(\mathrm{Cu}_{2} \mathrm{O}\). (d) It reacts with \(\mathrm{NaOH}\) and glucose to give \(\operatorname{Cu}_{2} O\)
Short Answer
Step by step solution
Understand the reaction
Check reaction with KI
Analyze reaction with KCl
Confirm reaction with NaOH and glucose
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Decomposition Reaction
- Chemical equation: \(2\text{CuSO}_4 \rightarrow 2\text{CuO} + 2\text{SO}_2 + \text{O}_2\)
- Energy input: Heat is necessary to initiate the decomposition.
- Products: Copper oxide, sulfur dioxide, and oxygen gas.
Precipitate Formation
- Chemical equation: \(\text{CuSO}_4 + 2\text{NaOH} \rightarrow \text{Cu(OH)}_2 \downarrow + \text{Na}_2\text{SO}_4\)
- Precipitate: \(\text{Cu(OH)}_2\) appears as a blue solid suspended in the mixture.
Displacement Reaction
- Chemical equation: \(2\text{CuSO}_4 + 4\text{KI} \rightarrow \text{Cu}_2\text{I}_2 + 2\text{K}_2\text{SO}_4 + \text{I}_2\)
- Observation: The formation of iodine is observed as a brown coloration in the solution.
- Products: Cuprous iodide, iodine, and potassium sulfate.
Color Changes
- Reaction with KI: The formation of iodine leads to a noticeable brown coloration in the solution.
- Reaction with NaOH: There is a transition from the original color of copper sulfate solution to a blue precipitate of copper hydroxide.
- Further reaction with Glucose: The reduction of copper hydroxide to cuprous oxide results in a red precipitate, marking yet another color change.