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Chapter 6: Problem 171

March rhe following: Column I \(\quad\) Column II A. \(\mathrm{H}_{2} \mathrm{SO}_{5}\) (p) \(\mathrm{S}-\mathrm{S}\) linkage B. \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{8}\) (q) \(+6\) oxidation state C. \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{6}\) (r) Peroxy linkage D. \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\) (s) \(-2\) oxidation stare

Short Answer

Expert verified
A - r, B - p, C - q, D - s.

Step by step solution

01

Identify structural features

Examine each compound in Column I and recognize any unique structural features that help in matching with Column II. For example, identify peroxy linkage (O-O bond) or S-S linkage present in compounds.
02

Match compound with peroxy bond

Recognize that peroxy linkage is an O-O bond. - Compound A, \(\mathrm{H}_{2} \mathrm{SO}_{5}\), contains a peroxy linkage. Therefore, match it with (r) Peroxy linkage.
03

Match compound with S-S linkage

Look for the S-S bond typically present in compounds with disulfur units. - Since \(\mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{8}\) has this feature, it matches with (p) \(\mathrm{S}-\mathrm{S}\) linkage.
04

Determine sulfur oxidation state

Determine which oxidation states match each compound by calculating the oxidation state of sulfur. - In \(\mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{6}\), sulfur is in the +6 oxidation state. Thus, it matches with (q) \(+6\) oxidation state.
05

Match compound with -2 oxidation state

For the compound \(\mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}\), recognize the oxidation state of S is typically -2, matching it with (s) \(-2\) oxidation state.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Peroxy Linkage
The peroxy linkage is an essential feature in some chemical compounds, characterized by the presence of an oxygen-oxygen (O-O) bond. This bond appears in compounds known as peroxides. The most common example is hydrogen peroxide, but in the context of sulfur chemistry, it manifests in compounds like \(\mathrm{H}_2 \mathrm{SO}_5\), which contains this distinctive linkage.
  • In the molecular structure, the peroxy linkage can increase the compound's reactivity due to the relatively weak oxygen-oxygen bond.
  • It's a key identifier when examining various sulfur-containing compounds, especially in determining their unique properties and reactivities.
  • Compounds with peroxy linkages are often more oxidizing than similar compounds without the linkage, which is crucial in both natural and industrial processes.
Recognizing peroxy linkages aids in predicting the chemical behavior of compounds, especially their oxidative capabilities.
S-S Linkage
An S-S linkage, also known as a disulfide bond, occurs when two sulfur atoms are covalently bonded together. This is a significant feature in many sulfur-containing compounds. For example, the compound \(\mathrm{H}_2 \mathrm{S}_2 \mathrm{O}_8\) possesses such a linkage.
  • Disulfide bonds are prevalent in proteins, where they play a crucial role in maintaining structural integrity. However, in inorganic chemistry, they are found in a variety of compounds, often influencing their stability and reactivity.
  • The presence of an S-S linkage can give the compound notable chemical properties, like increased resistance to reduction processes.
  • Understanding the occurrence of S-S linkages is crucial for predicting interactions in both synthetic compounds and naturally occurring molecules.
Hence, identifying S-S linkages is a fundamental step in analyzing sulfur chemistry.
Inorganic Compounds
Inorganic compounds encompass a wide variety of substances that primarily lack carbon-hydrogen bonds. They include oxides, sulfates, phosphates, and most importantly for this discussion, sulfur compounds like sulfates and sulfides.
  • These compounds are not only crucial in industrial processes but also in biological systems where they may play roles in metabolism and cellular functions.
  • Sulfur-based inorganic compounds have diverse applications, from fertilizers to pharmaceuticals, due to their versatile chemical behaviors.
  • Understanding the structural and chemical properties of these compounds can aid in developing new materials and solutions in various fields, such as energy storage and environmental engineering.
Studying inorganic compounds, especially those involving sulfur, involves looking at their oxidation states, linkages, and unique behaviors in different environments.
Sulfur Chemistry
Sulfur chemistry is a fascinating field that explores the behavior and characteristics of sulfur and its compounds. This branch of chemistry covers a vast array of phenomena due to sulfur's ability to exist in multiple oxidation states and to form various bonds.
  • Sulfur compounds, such as sulfates, sulfides, and oxoacids, contribute significantly to both industrial and biological chemistry.
  • Sulfur's versatility is evident through its ability to engage in different bonding patterns, like \(\mathrm{S}-\mathrm{S}\) and \(\mathrm{O}-\mathrm{O}\) linkages, illustrating its unique chemical flexibility.
  • The study of sulfur chemistry helps in understanding critical processes like vulcanization of rubber, synthesis of fertilizers, and even biological functions such as enzyme activities.
Being familiar with sulfur chemistry is not only essential for academic purposes but also for various practical applications in industry and technology.

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Most popular questions from this chapter

The number of \(\mathrm{S}-\mathrm{S}\) bonds in sulphur trioxidc rrimer \(\left(\mathrm{S}_{3} \mathrm{O}_{9}\right)\) is (a) Throc (b) Two (c) One (d) Zcro

(A): \(\mathrm{SO}_{3}\) has a planar structure. (R): \(S\) atom in \(\mathrm{SO}_{3}\) is \(\mathrm{sp}^{2}\) hybridized and \(\mathrm{O}-\mathrm{S}-\) O bond angle is \(120^{\circ}\).

In the manufacturc of sulphuric acid by contact proccss, Tyntall hox is uscel ro (a) rcmove impurirics (b) filrer dust particlcs (c) test the presence of dust particles (d) convert \(\mathrm{SO}_{2}\) co \(\mathrm{SO}_{3}\)

Given that hypohalous acids form by the following reaction $$ \begin{aligned} \mathrm{X}_{2}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(1) \rightleftharpoons & \mathrm{HOX}(\mathrm{aq})+\mathrm{H}^{\prime}(\mathrm{aq}) \\ &+\mathrm{X}(\mathrm{a} q) \end{aligned} $$ Which of the following changcs will incrcasc the yicla of I IOX? (a) \(\Lambda \mathrm{dd} \mathrm{X}^{-}\) (b) \(\Lambda \mathrm{dd}\) water (c) Increase rhe pIl (ct) Dccrcasc rhe ptI

The gas \(\mathrm{O}_{3}\) (ozone) can not oxidize (a) \(\mathrm{KI}\) (b) FeSO (c) \(\mathrm{KMnO}_{4}\) (d) \(\mathrm{K}_{2} \mathrm{MnO}\)
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