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Reddish brown (chocolate) precipitate are formed by mixing solutiors contairting, respectively: (a) \(\mathrm{Ba}^{2}\) and \(\mathrm{SO}_{4}^{2}\) ions (b) \(\mathrm{Cu}^{2 \mathrm{t}}\) and \(\mathrm{IFc}(\mathrm{CN})_{6} \mathrm{~J}^{-1}\) ions (c) \(\mathrm{Pb}^{2-}\) and \(\mathrm{SO}_{4}^{2-}\) ions (d) \(\mathrm{Pb}^{2-}\) and \(\mathrm{I}^{-}\) jors.

Short Answer

Expert verified
(b) Cu虏鈦 and K鈧刐Fe(CN)鈧哴 form a reddish-brown precipitate.

Step by step solution

01

Analyze the color and precipitate

To solve this exercise, we need to identify which combination of ions results in a reddish-brown precipitate. Common reddish-brown precipitates include iron(III) hydroxide (Fe(OH)鈧) and copper(I) oxide (Cu鈧侽), but in the context of the provided ions, the key option is likely related to iron compounds.
02

Evaluate the ion combinations

Now, we evaluate each option: - (a) Ba虏鈦 and SO鈧劼测伝 result in a white precipitate of BaSO鈧. - (b) Cu虏鈦 and K鈧刐Fe(CN)鈧哴 (Hexacyanoferrate) can form a reddish-brown precipitate of copper hexacyanoferrate. - (c) Pb虏鈦 and SO鈧劼测伝 form a white precipitate of PbSO鈧. - (d) Pb虏鈦 and I鈦 form a yellow precipitate of PbI鈧.
03

Select the correct combination

Based on the analysis from previous steps, the combination that results in a reddish-brown precipitate is (b) Cu虏鈦 and K鈧刐Fe(CN)鈧哴. This reaction is known to produce a reddish-brown precipitate.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Precipitate Reactions
Precipitation reactions occur when two solutions containing soluble salts are mixed, resulting in the formation of an insoluble solid called a precipitate. This process is fundamental in inorganic chemistry because it allows the selective separation of ions. To identify a precipitate reaction, we generally rely on solubility rules. These rules help us predict the formation of insoluble compounds. For example, most sulfate salts are soluble, but exceptions like barium sulfate (\(\text{BaSO}_4\)) and lead sulfate (\(\text{PbSO}_4\)) form precipitates.
  • When barium ions (\(\text{Ba}^{2+}\)) meet sulfate ions (\(\text{SO}_4^{2-}\)), they form a white precipitate.
  • Lead ions (\(\text{Pb}^{2+}\)) paired with iodide ions (\(\text{I}^{-}\)) create a yellow precipitate, \(\text{PbI}_2\)
  • .
Each of these reactions confirms the combination of certain ions forming a solid, thus illustrating our understanding of solubility in aqueous solutions. As we dissect various reactions and observe the precipitates, we decipher which combinations create insoluble substances, gaining insight into their chemical behavior.
Copper Complexes
Copper complexes are pivotal in the study of inorganic chemistry. They form when copper ions combine with various ligands to create often colorful compounds. Copper typically exists in two states, \(\text{Cu}^{+}\) and \(\text{Cu}^{2+}\).
  • The copper(II) ion (\(\text{Cu}^{2+}\)) can interact with hexacyanoferrate ions (\([\text{Fe(CN)}_6]^{4-}\)), forming a copper hexacyanoferrate complex.
  • This is a common example of a coordinate bond formation where the ligands donate electron pairs to the central metal ion forming a stable complex.
The process provides a rich palette of colors, with these complexes showing distinct hues depending on the chemicals involved. In the case of copper hexacyanoferrate, the resulting complex is notable for its reddish-brown coloration. Understanding these reactions enhances our ability to predict and manipulate chemical behavior through complex formation.
Color Identification in Reactions
Identifying colors in chemical reactions is a practical aspect of chemistry, providing visual confirmation of chemical changes. Different colors emerge due to the nature of compounds formed, especially those involving transition metals like copper. Reddish-brown formations point towards specific types of compounds. For example:
  • Copper(I) oxide, \(\text{Cu}_2\text{O}\), is one example known for its reddish pigmentation.
  • In our specific context, the copper hexacyanoferrate complex forms a reddish-brown precipitate, helping chemists visually identify the product of a reaction.
Color provides intuitive insights into the chemical compositions and helps distinguish between different reactions. As such, recognizing these color changes can significantly aid in analyzing and confirming the nature of specific mixtures in inorganic chemistry experiments.

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