Chapter 1: Problem 71
Which of rhe following molccule is planar? (a) \(\mathrm{Cll}_{\mathrm{A}}\) (b) \(\mathrm{NH}_{3}\) (c) \(\mathrm{C}_{2} 1 \mathrm{H}_{4}\) (d) \(\mathrm{SiCl}_{\text {s }}\)
Short Answer
Expert verified
(c) \( C_2H_4 \) is planar.
Step by step solution
01
Determine Planarity
For a molecule to be planar, all atoms should lie in the same geometric plane. Consider each molecule's geometry to determine if this is the case.
02
Analyze Each Molecule
(a) For \ \( \mathrm{Cl}_2 \), we only have a diatomic molecule which by definition of structure, must be linear and hence planar.(b) \[ NH_3 \] adopts a trigonal pyramidal structure due to sp3 hybridization of the nitrogen atom, causing the molecule to be non-planar.(c) \[ C_2H_4 \] (ethylene) is formed by two carbon atoms joined with a double bond, each bonded to two hydrogen atoms. In ethylene, each carbon uses sp2 hybridized orbitals, resulting in a planar (trigonal planar) molecule.(d)\[ SiCl_4 \] is tetrahedral in shape due to the sp3 hybridization of the silicon atom, which makes it a non-planar structure.
03
Identify Planar Molecule
Based on the above analysis, identify the molecule(s) where all constituent atoms lie in the same plane. From our analysis, only \ \( C_2H_4 \) is planar.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Planar Molecules
Planar molecules are a fascinating area of chemistry where all the atoms in a molecule lie flat in a single plane. This unique arrangement allows for specific physical and chemical behaviors, distinguishing them from molecules with three-dimensional structures. Molecules that are planar generally exhibit certain characteristics:
- They have specific hybridization states, typically involving sp2 hybridization.
- The molecular geometry restricts the movement of the atoms entirely to a single plane, enhancing stability in certain reactions.
- Planar structures often allow better overlap of \(\pi\) orbitals, which is crucial in forming \(\pi\) bonds as seen in \(C_2H_4\) (ethylene).
sp2 Hybridization
Hybridization is an essential concept that helps better understand the shape and bonding in molecules. The sp2 hybridization occurs when one s orbital mixes with two p orbitals, resulting in three equivalent orbitals shaped in a plane.Key characteristics of sp2 hybridization include:
- Three sp2 hybrid orbitals lie 120 degrees apart, forming a trigonal plane.
- Each hybridized orbital can form sigma bonds, while the unhybridized p orbital can form a \(\pi\) bond.
- This hybridization is commonly seen in molecules like ethylene, where double bonds play a pivotal role in structure and reactivity.
Trigonal Planar Structure
Characterized by its specific arrangement of atoms, a trigonal planar structure emerges when there is sp2 hybridization. In this geometry, one central atom connects directly to three other atoms, forming a plane.Features of the trigonal planar structure include:
- Bond angles of approximately 120 degrees, which are evenly distributed around the central atom.
- The symmetry and even distribution of electron density create reduced steric strain compared to other shapes.
- Molecules with this geometry can exhibit unique properties like enhanced rigidity and potentially unique chemical pathways.