Chapter 4: Problem 8
Draw the Lewis diagram for the covalent bonding in \(\mathrm{H}_{2} \mathrm{~S}\). How many bonding electrons and nonbonding electrons are in the molecule?
Short Answer
Expert verified
4 bonding electrons, 4 nonbonding electrons.
Step by step solution
01
Identify the Atoms and Their Valence Electrons
First, determine the number of valence electrons for each atom in the molecule. Hydrogen (H) has 1 valence electron, and there are 2 hydrogen atoms, contributing 2 electrons. Sulfur (S) has 6 valence electrons. Thus, the total number of valence electrons in the \(\text{H}_{2}\text{S}\) molecule is \(2 + 6 = 8\) electrons.
02
Distribute Electrons Around the Central Atom
In a Lewis structure, the least electronegative atom typically goes in the center, which is sulfur in this case. Distribute the 8 valence electrons around the sulfur atom by making sure the hydrogen atoms each have 2 electrons, satisfying their duet rule. The rest of the electrons are placed as lone pairs on the sulfur atom.
03
Draw the Lewis Structure
Place a single bond (2 electrons) between each hydrogen atom and the central sulfur atom. This accounts for 4 electrons (2 electrons for each of the two bonds). The remaining 4 electrons are placed as two lone pairs on sulfur.
04
Count Bonding and Nonbonding Electrons
In the Lewis structure of \(\text{H}_{2}\text{S}\), there are 2 bonding pairs of electrons (or 4 bonding electrons) present in the molecule, forming bonds between sulfur and each hydrogen atom. There are also 2 lone pairs on the sulfur atom, resulting in 4 nonbonding electrons.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Covalent Bonding
Covalent bonding is a type of chemical bond where atoms share pairs of electrons to achieve stability in their outer electron shell. In the molecule hydrogen sulfide
(
H
â‚‚
S
), this kind of bonding is exemplified between the hydrogen and sulfur atoms.
- This molecule demonstrates how covalent bonding allows different elements to combine and form a stable group, by filling the electron void in their outer shells.
- Hydrogen atoms, each having one electron, share their electrons with the sulfur atom.
Valence Electrons
Valence electrons play a critical role in determining how atoms bond and interact. They are the outermost electrons in an atom and are essential in the formation of chemical bonds. In our example of
H
â‚‚
S, each element contributes valence electrons to the molecule.
- Hydrogen, with 1 valence electron per atom, adds a total of 2 electrons when considering its two hydrogen atoms.
- Sulfur brings 6 valence electrons to the table.
Electron Pair Geometry
The concept of electron pair geometry involves understanding how pairs of electrons arrange themselves around a central atom to minimize repulsion and maximize stability. In
H
â‚‚
S, this geometry is determined largely by the electron pairs held by the sulfur.
- Sulfur, sitting at the center of the molecule, is surrounded by two bonding electron pairs and two nonbonding (lone) pairs.
- The electron pairs try to push away from each other, creating a three-dimensional arrangement.