Chapter 10: Problem 3
Which solute combinations can make a buffer? Assume all are aqueous solutions. 1\. \(\mathrm{HCl}\) and \(\mathrm{NaCl}\) 2\. \(\mathrm{HNO}_{2}\) and \(\mathrm{NaNO}_{2}\) 3\. \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) and \(\mathrm{HNO}_{3}\) 4\. \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) and \(\mathrm{NH}_{3}\)
Short Answer
Step by step solution
Understanding Buffers
Analyzing Pair 1
Analyzing Pair 2
Analyzing Pair 3
Analyzing Pair 4
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Weak Acid
Weak acids are important in buffer systems because they can react with added bases to maintain the stability of the solution's pH. What makes an acid 'weak'? - A weak acid does not release all of its ions in water. This is typically due to the nature of the acid and its equilibrium in water. - Common examples include acetic acid ( ce{CH3COOH} ) and nitrous acid ( ce{HNO2} ). In a buffer system, the presence of a weak acid allows it to respond to changes in pH, absorbing added bases and keeping the overall pH stable. This is essential in many biological and chemical processes.
Conjugate Base
The importance of conjugate bases in buffer solutions: - Conjugate bases can accept protons, allowing them to react with any added acid to the buffer, thus neutralizing its effect. - For instance, when ce{HNO2} (nitrous acid) donates a proton, it transforms into its conjugate base, ce{NO2-} . The balance between a weak acid and its conjugate base in a solution is what gives a buffer its ability to resist changes in pH. This balance ensures that any added acids or bases are effectively neutralized.
Weak Base
Traits of a weak base include: - Incomplete ionization in water, which means not all of its particles dissociate into ions. - Common examples are ammonia ( ce{NH3} ) and potassium carbonate ( ce{K2CO3} ). In a buffer system, weak bases accept hydrogen ions from any strong acid that is introduced, preventing drastic shifts in pH. This characteristic is essential for maintaining equilibrium and ensuring reactions in solutions proceed predictably.