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Calculate the fraction of association (伪) for 1.00 脳 10-1, 1.00 脳10-2, and 1.00 脳10-12 M sodium acetate. Does 伪 increase or decrease with dilution?

Short Answer

Expert verified

The fraction of dissociation, a=0.0076%,0.024%,and0.57%.

Step by step solution

01

Definition of association.

It is defined as the aggregation of atoms or molecules into larger units.

02

Step: Consider a reaction.

CH3CO2-+H2OCH3CO2H+OH-[CH3CO2-]=F-x[CH3CO2H]=[OH-]=x

03

Calculating value of Kb .

We will use this equation for following:

Kb=x2F-xF=10-1x=7.610-6F=10-2x=2.410-6F=10-12,

We can see that dilution is so high that pH=7we can use the following:

localid="1654945563356" HA=KbA-OH-=5.710-3A-

04

Calculate fraction of dissociation.

a=HAHA+A-=5.710-3A-5.710-3A-+A-a=0.57%

Now, we can conclude that more the dilution of solution greater the fraction of dissociation.

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