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Explain the following statement: 鈥淭he validity of an analytical

result ultimately depends on knowing the composition of some primary standard.鈥.

Short Answer

Expert verified

The qualities of the primary standard have a significant impact on the accuracy of a chemical analysis.

Step by step solution

01

Define the accuracy and measurement.

The precision of a single measurement is referred to as accuracy. The measurement's accuracy is determined by comparing it to the true or acceptable value. Like reaching the centre of a bullseye, an accurate measurement is close to the true value.

02

 Explain the statement.

A primary standard is a very pure material that acts as a compound's reference material.

In a chemical analysis, it is critical that an analyst understands or is familiar enough with the main standard to which he or she is referring, since if the wrong primary standard is chosen, all of the procedures and calculations will be useless.

The qualities of the primary standard have a significant impact on the accuracy of a chemical analysis.

It's vital to have a clear understanding of your analysis's purpose so you can pick the major standard that best matches your methodology.

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Most popular questions from this chapter

Managing a salt-water aquarium. A tank at the New Jersey State Aquarihas

a volume of 2.9million liters.5Bacteriaare used to remove nitrate

that would otherwise build up to toxic levels. Aquarium water is first pumped into

a 2700-Ldesecration tank containing bacteria that consumeO2in the presence

of added methanol:

2CH3OH+3O2Bacteria2CO2+4H2O

Anoxic (deoxygenated) water from the desecration tank flows into a gentrification reactor containing colonies of Pseudomonas bacteria in a porous medium. Methanol is injected continuously and nitrate is converted into nitrite and then into nitrogen:

3NO3-+CH3OHBacteria3NO2-+CO2+2H2Onitrate2NO3-+CH3OHBacteriaN2+CO2+H2O+2OH-

a) Desecration can be thought of as a slow, bacteria-mediated titration

ofO2bylocalid="1655109035857" CH3OH. The concentration oflocalid="1655109054860" O2in seawater at localid="1655109040090" 24C is localid="1655109045111" 220渭尘 .

How many liters oflocalid="1655109050648" (FM32.04,density=0.791g/mL)are required

by Reaction 1for 2.9 million liters of aquarium water?

b) Write the net reaction showing nitrate plus methanol going to nitrogen.

How many liters of localid="1655109058452" CH3OHare required by the net reaction for 2.9 million

liters of aquarium water with a nitrate concentration of localid="1655109062338" 8100渭尘?

c) In addition to consuming methanol for Reactions 1 through 3, the

bacteria require 30% more methanol for their own growth. What is the

total volume of methanol required to denitrify 2.9 million liters of

aquarium water?

What is wrong with this procedure? According to Table 7-1, carbonate can be measured by a Volhard titration. Removal of the precipitate is required. To analyse an unknown solution of, Na2CO3, l acidified the solution with freshly boiled and cooled HNO3to give ,0.5 M HNO3. Then I added excess standard, but no Ag2CO3precipitate formed. What happened?

A solid mixture weighing 0.05485 gcontained only ferrous ammonium sulfate and ferrous chloride. The sample was dissolved in 1MH2SO4, and the Fe2+ required 13.39mLof 0.01234MCe4+for complete oxidation toFe3+(Ce4++Fe2+Ce3++Fe3+). Calculate the weight percent CI ofin the original sample.

Why are ultrapure acid solvents required to dissolve samples

for trace analysis?

A mixture having a volume of 10.00mLand containing 0.1000MAg+and0.1000MHg22+was titrated with 0.1000MKCNto precipitate Hg2(CN)2and AgCN.

(a) Calculate pCN-at each of the following volumes of added KCN: 5.00,10.00,15.00,19.90,20.10,25.00,30.00,35.00mL

(b) Should any AgCN be precipitated at 19.90mL?

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