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(a) What types of solutes are typically separated with a poly(dimethylsiloxane)-coated open tubular column?

(b) What types of solutes are typically separated with a poly(ethylene glycol)-coated open tubular column?

(c) What types of solutes are typically separated with a porous-layer open tubular column?

Short Answer

Expert verified

(a.)

Selecting a liquid stationary phase depends on the rule "like dissolves like". This signifies that the Polarity of the column must be the same as that of the solute

(b.) Solutes that are typically separated with a poly(dimethylsiloxane)-coated open tubular column are the following (based on Table 24-1)

(c.) Porous-layer columns contain porous solid particles with large surface area that adhere to the column wall. The highly retentive surface of the particles serve as the active stationary phase. Solutes that are typically separated with a porous-layer open tubular column areHe,Ar2O2,N2,CH4andCO. Furthermore, porous polymers, high-surface-area carbon , and alumina (Al2O3)can separate hydrocarbons in gas-solid adsorption chromatography.

Step by step solution

01

To find the types of solutes are typically separated with a poly(dimethylsiloxane)-coated open tubular column 

(a)

Selecting a liquid stationary phase depends on the rule "like dissolves like". This signifies that the Polarity of the column must be the same as that of the solute

02

find the types of solutes are typically separated with a poly(ethylene glycol)-coated open tubular column

03

Step 3: types of solutes are typically separated with a porous-layer open tubular column

(C)

Porous-layer columns contain porous solid particles with large surface area that adhere to the column wall. The highly retentive surface of the particles serve as the active stationary phase. Solutes that are typically separated with a porous-layer open tubular column areHe,Ar2O2,N2,CH4andCO. Furthermore, porous polymers, high-surface-area carbon , and alumina (Al2O3)can separate hydrocarbons in gas-solid adsorption chromatography.

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Most popular questions from this chapter

(a) When a solution containing234mg of pentanol (FM 88.15) and237mg of 2,3 -dimethyl-2-butanol (FM 102.17) in10.0ml was separated, relative peak areas were pentanol: 2,3 -dimethyl-2-butanol = 0.913 : 1.00. Considering pentanol to be the internal standard, find the response factor for 2,3 -dimethyl-2-butanol.

(b) Use Equation 24-8 to find the areas for pentanol and 2,3 -dimethyl-2-butanol in Figure 24-8.

(c) The concentration of pentanol internal standard in the unknown solution was93.7mM . What was the concentration of 2,3 -dimethyl2-butanol?

(a) What are the characteristics of an ideal carrier gas?

(b) Why do H2 and He allow more rapid linear velocities in gas chromatography thanN2 does, without loss of column efficiency (Figure 24-11)?

(a) Use Trouton's rule, Hvap(88Jmol-1K-1)Tbp, to estimate the enthalpy of vaporization of octane (b.p. 126).

(b) Use the form of the Clausius-Clapeyron equation below to estimate the vapor pressure of octane at the column temperature in Figure 24-9(70C)

In(P1P2)=-(HvapR)(1T1-1T2)

(c) Calculate the vapor pressure for hexane (b.p. 69C) at70C

(d) What is the relationship between solute vapor pressure and retention?

(e) Why is the technique called "gas chromatography鈥 if retained analytes are only partially vaporized?

When 1.06 mmol of 1-pentanol and 1.53 mmol of 1-hexanol were separated by gas chromatography, they gave peak areas of 922 and 1570 units, respectively. When 0.57 mmol of pentanol was added to an unknown containing hexanol, the peak areas were 843:816 (pentanol:hexanol). How much hexanol did the unknown contain?

(a) What are the advantages and disadvantages of temperature programming in gas chromatography?

(b) What is the advantage of pressure programming?

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