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Problem 34

How many milliliters of \(3.00 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) are required to react with \(4.35 \mathrm{~g}\) of solid containing \(23.2 \mathrm{wt} \% \mathrm{Ba}\left(\mathrm{NO}_{3}\right)_{2}\) if the reaction is \(\mathrm{Ba}^{2+}+\mathrm{SO}_{4}^{2} \rightarrow \mathrm{BaSO}_{4}(s) ?\)

Problem 35

How many grams of \(0.491\) wt\% aqueous \(\mathrm{HF}\) are required to provide a \(50 \%\) excess to react with \(25.0 \mathrm{~mL}\) of \(0.0236 \mathrm{M} \mathrm{Th}^{4+}\) by the reaction \(\mathrm{Th}^{4+}+4 \mathrm{~F}^{-} \rightarrow \mathrm{ThF}_{4}(s)\) ?

Problem 36

Explain the following statement: "The validity of an analytical result ultimately depends on knowing the composition of some primary standard."

Problem 37

Distinguish between the terms end point and equivalence point.

Problem 38

How does a blank titration reduce titration error?

Problem 39

What is the difference between a direct titration and a back titration?

Problem 40

What is the difference between a reagent grade chemical and a primary standard?

Problem 41

Why are ultrapure acid solvents required to dissolve samples for trace analysis?

Problem 42

How many milliliters of \(0.100 \mathrm{M} \mathrm{KI}\) are needed to react with \(40.0 \mathrm{~mL}\) of \(0.0400 \mathrm{M} \mathrm{Hg}_{2}\left(\mathrm{NO}_{3}\right)_{2}\) if the reaction is \(\mathrm{Hg}_{2}^{2+}+2 \mathrm{I}^{-} \rightarrow\) \(\mathrm{Hg}_{2} \mathrm{I}_{2}(s) ?\)

Problem 43

For Reaction 1-7, how many milliliters of \(0.1650 \mathrm{M} \mathrm{KMnO}_{4}\) are needed to react with \(108.0 \mathrm{~mL}\) of \(0.1650 \mathrm{M}\) oxalic acid? How many milliliters of \(0.1650 \mathrm{M}\) oxalic acid are required to react with \(108.0 \mathrm{~mL}\) of \(0.1650 \mathrm{M} \mathrm{KMnO}_{4}\) ?

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