Chapter 7: Problem 46
For an elementary reaction, \(X(g) \rightarrow Y(g)+Z(g)\) the half life period is \(10 \mathrm{~min}\). In what period of time would the concentration of \(X\) be reduced to \(10 \%\) of original concentration ? (a) \(20 \mathrm{Min}\). (b) \(33 \mathrm{Min}\) (c) \(15 \mathrm{Min}\) (d) \(25 \mathrm{Min}\)
Short Answer
Step by step solution
Understanding the Concept of Half-Life
Calculating the Number of Half-Lives
Solving for the Number of Half-Lives
Finding the Total Time
Selecting the Correct Answer
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
First-Order Reaction Kinetics
In mathematical terms, the rate of a first-order reaction is expressed as \( Rate = k[A] \), where \( [A] \) represents the concentration of your reactant A, and \( k \) is the rate constant, unique to each reaction at a given temperature. The magical thing about first-order reactions is their half-life, a time interval in which the concentration of the reactant is halved, remains constant regardless of the starting concentration. This property is tremendously useful because it gives us a reliable measure to predict how long it will take for the reactant to diminish to a certain level, which in the context of our problem, allows us to estimate when only 10% of the original concentration of X would remain.
Elementary Reaction
For instance, our reaction \( X(g) \rightarrow Y(g) + Z(g) \) suggests that one molecule of X is converted directly into molecules of Y and Z. The rate law for this first-order elementary reaction indicates that the rate at which X is consumed is directly proportional to its concentration, which we have already seen is key for determining how the reaction proceeds over time. Additionally, for an elementary first-order reaction, the concept of half-life becomes particularly straightforward, as it does not change even as the concentration of X decreases.
Concentration Reduction in Reactions
In the context of chemical kinetics, to calculate how long it will take for the concentration to drop to a certain percentage—let's say 10% of the original—we use the concept of half-life. With each passing half-life period, the concentration of our reactant halves. So, by calculating the number of half-lives required to reach the desired concentration (10% in our case), we can find out the total time needed for this reduction.