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Match the following Column 1 A. Normality B. Molarity C. Molality D. Concentration Column II (p) gram of solute in one lit. (q) no. of mole in one \(\mathrm{kg}\) solvent (r) no. of mole in one lit. (s) no. of \(\mathrm{w} / \mathrm{E}\) in one lit

Short Answer

Expert verified
A → s, B → r, C → q, D → p

Step by step solution

01

Understand the terms in Column I

First, let's recall what each term in Column I means: - **Normality (A):** A measure of concentration equivalent to the number of equivalents per liter of solution. - **Molarity (B):** Number of moles of solute per liter of solution. - **Molality (C):** Number of moles of solute per kilogram of solvent. - **Concentration (D):** General measure of the amount of solute in a given volume or mass of solvent or solution.
02

Match Normality to Column II

Normality in Column I is matched with the expression "no. of \( \frac{w}{E} \) in one liter" from Column II. This is because Normality considers the number of equivalents (\( w/E \)) of solute per liter of solution. Thus, \( \text{A} \rightarrow \text{s} \).
03

Match Molarity to Column II

Molarity represents the number of moles of solute per liter of solution. In Column II, "no. of mole in one lit." matches this definition. Therefore, \( \text{B} \rightarrow \text{r} \).
04

Match Molality to Column II

Molality is defined as the number of moles of solute per kilogram of solvent. Column II provides "no. of mole in one kg solvent," which corresponds to molality. Hence, \( \text{C} \rightarrow \text{q} \).
05

Match Concentration to Column II

Concentration is a more general term, often referring to the amount of solute per unit volume or mass of solvent or solution. Here, "gram of solute in one lit." fits this description. Therefore, \( \text{D} \rightarrow \text{p} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Normality
Normality is a concept used to express the concentration of a solution but focuses specifically on equivalents. Equivalents are a way of accounting for the reactive capacity of molecules, ions, or atoms in a chemical reaction. For acids and bases, one equivalent is the amount that can furnish or react with one mole of hydrogen ions. For salts, it refers to the amount that can furnish one mole of cations or anions. Therefore, normality is helpful when dealing with reactions and stoichiometry involving equivalent weights.
To calculate normality (), you can use the formula:\[ N = \frac{w}{E} \] where \( w \) is the number of equivalence and \( E \) is the equivalent weight of the solute. This is measured per liter of solution, much like molarity, but adjusted to show reactive capability. It's commonly used in titrations and chemical reactions, where understanding the precise effect of a solution is crucial.
Molarity
Molarity is one of the most common ways to express concentration. It refers to the number of moles of solute dissolved in one liter of solution. This measure is often represented with the unit "M" or mol\( / \)L. In practical applications, molarity helps in understanding how many molecules or ions are present in a solution, which is essential for calculating reagent amounts in chemical reactions or determining reaction rates.
  • The formula for calculating molarity (M) is:\[ M = \frac{\text{{moles of solute}}}{\text{{liters of solution}}} \]
Molarity provides a straightforward way to prepare solutions of accurate concentrations needed for various scientific purposes, ranging from research to industrial processes. It is crucial when precise concentrations are required, like when predicting the outcome of a chemical reaction.
Molality
Molality is another measure of concentration that differs from molarity by using the mass of the solvent instead of the total volume of the solution. It is particularly useful in conditions involving temperature changes since it does not vary with temperature, unlike molarity, which can change because the volume of liquid expands with heat. Molality is defined as the number of moles of solute per kilogram of solvent.
  • Here’s the formula for molality (\( m \)):\[ m = \frac{\text{{moles of solute}}}{\text{{kilograms of solvent}}} \]
Because it depends strictly on the mass of the solvent, molality is employed in calculations involving colligative properties, such as boiling point elevation and freezing point depression. It provides an accurate measure of concentration in any physical state, making it a valuable tool in situations where precision is non-negotiable.

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Most popular questions from this chapter

Match the following: Column | A. Osmotic pressure B. Relative lowering of V.P. C. Elevation in B.P. D. Depression in F.P. Column II (p) Colligative Property (q) Ostwald Walker Method (r) \(\alpha 1 /\) molecular weight of solute (s) Ebullioscopic constant (t) Cryoscopic constant

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