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A mechanism for a naturally occurring reaction that destroys ozone is: Step I: \(\mathrm{O}_{3}(\mathrm{~g})+\mathrm{HO}(\mathrm{g}) \rightarrow \mathrm{HO}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g})\) Step II: \(\mathrm{HO}_{2}(\mathrm{~g})+\mathrm{O}(\mathrm{g}) \rightarrow \mathrm{HO}(\mathrm{g})+\mathrm{O}_{2}(\mathrm{~g})\) Which species is a catalyst? a. \(\mathrm{O}\) b. \(\mathrm{O}_{3}\) c. \(\mathrm{HO}_{2}\) d. HO

Short Answer

Expert verified
The catalyst is HO.

Step by step solution

01

Identify intermediates and catalysts

A catalyst is a substance that is used in a reaction and then regenerated, while intermediates are produced in one step and consumed in another. We need to examine the species that appear in both reactions.
02

Analyze Step I

In Step I, \( \mathrm{HO} \) reacts with \( \mathrm{O}_{3} \) to produce \( \mathrm{HO}_{2} \) and \( \mathrm{O}_{2} \). Mark \( \mathrm{HO} \) as potentially a catalyst because it is consumed in this step.
03

Analyze Step II

In Step II, \( \mathrm{HO}_{2} \) reacts with \( \mathrm{O} \) to produce \( \mathrm{HO} \) and \( \mathrm{O}_{2} \). Observe that \( \mathrm{HO} \) is regenerated in this step, suggesting it serves as a catalyst.
04

Conclusion on Catalyst Identification

The species \( \mathrm{HO} \) is used in Step I and regenerated in Step II. It acts as a catalyst. Meanwhile, \( \mathrm{HO}_{2} \) is an intermediate since it is produced in Step I and consumed in Step II.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Intermediates in Reactions
In chemical reactions, intermediates are species that are formed during the reaction process but do not appear in the final products. They are important because they help in understanding how a reaction proceeds.

In the given ozone destruction mechanism, the intermediate is \( \mathrm{HO}_{2} \). During the reaction, it is produced in Step I when \( \mathrm{O}_{3} \) reacts with \( \mathrm{HO} \). It is then consumed in Step II as it reacts with \( \mathrm{O} \) to regenerate \( \mathrm{HO} \). This shows the transient nature of intermediates—they exist temporarily within the reaction sequence and do not appear in the overall equation for the reaction.

Intermediates can be thought of as hidden actors of the chemical world, facilitating transformations that do not directly show up in the main chemical equation. This is why detecting intermediates often requires techniques like spectroscopy to monitor reaction progress.
Ozone Destruction Mechanism
Ozone, \( \mathrm{O}_{3} \), plays a vital role in protecting life on Earth by absorbing harmful UV radiation from the sun. However, certain natural and human-influenced mechanisms can lead to its destruction.

The mechanism provided shows how \( \mathrm{HO} \) (hydroxyl radical) contributes to the breakdown of ozone. The process occurs through two steps:
  • Step I: The hydroxyl radical \( \mathrm{HO} \) reacts with ozone \( \mathrm{O}_{3} \) to form \( \mathrm{HO}_{2} \) and oxygen \( \mathrm{O}_{2} \).
  • Step II: The intermediate \( \mathrm{HO}_{2} \) then reacts with a monoatomic oxygen \( \mathrm{O} \) to regenerate \( \mathrm{HO} \) and produce more \( \mathrm{O}_{2} \).
Through this cycle, \( \mathrm{HO} \) acts as a catalyst in ozone destruction. The net effect of this mechanism is the conversion of \( \mathrm{O}_{3} \) to \( \mathrm{O}_{2} \), thus decreasing the ozone concentration in the atmosphere.

Understanding these mechanisms helps scientists develop strategies to protect the ozone layer from further depletion by managing variables that influence such chemical reactions.
Reaction Mechanisms
Reaction mechanisms detail the step-by-step processes through which reactants get transformed into products. They are crucial for understanding every reaction's kinetic and dynamic aspects.

In the described mechanism, each step elucidates how different species interact and transform:
  • Initially, each step breaks down the overall reaction into smaller, more manageable parts.
  • By identifying intermediates and catalysts, chemists can predict the behavior of the reaction over time.
  • Studying mechanisms guides us in finding efficient pathways or designing processes that can either enhance or inhibit certain reactions.
The accuracy of a proposed mechanism can dramatically impact the development of industrial and environmental applications. For example, understanding catalytic cycles in biological or atmospheric systems like ozone layer dynamics introduces interventions that mitigate harmful processes.

By breaking down reactions into individual steps and analyzing specific pathways, chemists can gain a deeper insight into the chemistry governing each transformation within any given mechanism.

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Most popular questions from this chapter

The basic theory behind Arrhenius's equation is that a. The activation energy and pre-exponential factor are always temperature- independent b. The rate constant is a function of temperature c. The number of effective collisions is proportional to the number of molecules above a certain threshold energy d. As the temperature increases, so does the number of molecules with energies exceeding the threshold energy.

If ' \(\mathrm{I}\) ' is the intensity of absorbed light and ' \(\mathrm{C}\) ' is the concentration of \(A B\) for the photochemical process \(\mathrm{AB}+\mathrm{hv} \rightarrow \mathrm{AB}^{*}\), the rate of formation of \(\mathrm{AB}^{*}\) is directly proportional to a. \(\mathrm{C}\) b. I c. \(\mathrm{I}^{2}\) d. C.I.

For the hypothetical second order reaction: \(\mathrm{A} \rightarrow\) Products, the general rate law is: Rate \(=\mathrm{k}[\mathrm{A}]^{2}\) How long is the third half life of the reaction if \([\mathrm{A}]_{0}\) is \(0.080 \mathrm{M}\) and the first half life is 22 minutes. a. \(48 \mathrm{~min}\) b. \(66 \mathrm{~min}\) c. \(88 \mathrm{~min}\) d. \(78 \mathrm{~min}\)

(A): Arrhenius equation explains the temperature dependence of rate of a chemical reaction. (R): Plots of log \(\mathrm{K}\) vs \(1 / \mathrm{T}\) are linear and the energy of activation is obtained from such plots.

Consider the following statements: (1) Rate of a process is directly proportional to its free energy change. (2) The order of an elementary reaction step can be determined by examining the stoichiometry. (3) The first order reaction describe exponential time coarse. Of the statements a. 1 and 2 are correct b. 1 and 3 are correct c. 2 and 3 are correct d. 1,2 and 3 are correct

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