Chapter 2: Problem 187
Match the following \(\begin{array}{ll}\text { Column I } & \text { Column II }\end{array}\) A. \(P \alpha 1 / V\) at constant \(T\) (p) Graham's law B. \(\mathrm{P} \alpha \mathrm{T}\) at constant \(\mathrm{V}\) (q) Gay Lussac's law C. \(\mathrm{V} \propto \mathrm{T}\) at constant \(\mathrm{P}\) (r) Charle's law D. \(V \alpha n\) at constant \(T\) (s) Boyle's law and \(\mathrm{P}\)
Short Answer
Step by step solution
Understand the Singular Concepts
Match "A" from Column I
Match "B" from Column I
Match "C" from Column I
Match "D" from Column I
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Boyle's Law
Imagine compressing a balloon—when you push down on it, the air inside has less space to occupy, and thus exerts more pressure against the balloon's walls.
- The formula is articulated as: \(P \propto \frac{1}{V}\), or in equation form, \(P_1 \times V_1 = P_2 \times V_2\).
- This law is integral in understanding how gases behave under different volume constraints, particularly in closed systems.
Gay-Lussac's Law
This means that if the temperature of a gas increases, so does its pressure, and vice versa. The key here is maintaining a constant volume. Think of a sealed metal can—it can burst when heated because the gas inside expands, raising the pressure.
- Expressed mathematically, the law is \(P \propto T\), which can be rewritten as \(\frac{P_1}{T_1} = \frac{P_2}{T_2}\).
- Converting temperature to a Kelvin scale is crucial, as it starts at absolute zero, offering a true baseline for calculations.
Charles' Law
This might be observed when heating a balloon; as the gas inside warms, the balloon expands, illustrating how temperature affects volume. This principle is clearly visible in everyday phenomena, such as the expansion of air in car tires during a hot day.
- The formula is typically shown as: \(V \propto T\), indicated by the equation \(\frac{V_1}{T_1} = \frac{V_2}{T_2}\).
- Here, temperature must also be measured in Kelvin.
Avogadro's Law
This underpins the principle that the volume of a gas is directly proportional to the number of moles it contains, influencing calculations in chemical reactions and stoichiometry.
- The law is given by \(V \propto n\), or represented in equation form as \(\frac{V_1}{n_1} = \frac{V_2}{n_2}\).
- This fundamental idea supports the molar volume concept of a gas, especially under standard conditions of temperature and pressure.
Ideal Gas Law
The law is represented by the formula \(PV = nRT\), where:
- \(P\) stands for pressure, measured in atmospheres (atm).
- \(V\) represents volume, typically in liters (L).
- \(n\) is the number of moles of gas.
- \(R\) is the universal gas constant, valued at approximately 0.0821 atm L/mol K.
- \(T\) indicates the absolute temperature in Kelvin (K).