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Which of the following is adsorbed in maximum amount by activated charcoal? a. \(\mathrm{N}_{2}\) b. \(\mathrm{CO}\) c. \(\mathrm{HCl}\) d. \(\mathrm{CO}_{2}\)

Short Answer

Expert verified
\(\mathrm{HCl}\) is adsorbed the most by activated charcoal.

Step by step solution

01

Understand Adsorption

Adsorption is a process where a solid is used for removing a substance from a gas or liquid. In this case, we are considering which gas is adsorbed the most by activated charcoal.
02

Consider Gas Properties

The extent to which gases are adsorbed by a solid such as activated charcoal is influenced by properties like molecular weight and critical temperature. Higher molecular weight and higher critical temperature usually increase adsorption.
03

Compare Molecular Sizes

The molecular weights of the gases provided are as follows: \(\mathrm{N}_2\) (28 g/mol), \(\mathrm{CO}\) (28 g/mol), \(\mathrm{HCl}\) (36.46 g/mol), and \(\mathrm{CO}_2\) (44 g/mol). Generally, larger molecules are adsorbed more readily due to greater van der Waals forces.
04

Analyze Critical Temperatures

The critical temperatures of the gases are: \(\mathrm{N}_2\) (126.2 K), \(\mathrm{CO}\) (132.9 K), \(\mathrm{HCl}\) (324.5 K), and \(\mathrm{CO}_2\) (304.2 K). Higher critical temperatures suggest a gas can be more easily condensed under pressure and thus are more readily adsorbed.
05

Conclusion

Based on both molecular size and critical temperature, \(\mathrm{HCl}\) is likely to be adsorbed the most by activated charcoal because it has the highest critical temperature and relatively large molecular weight.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Activated Charcoal
Activated charcoal is a form of carbon that has been processed to have small, low-volume pores. These pores increase the surface area available for adsorption processes. The primary function of activated charcoal is to adsorb substances, particularly gases and chemicals, due to its porous nature.

This substance is highly effective in adsorbing gases, which makes it useful for purification processes, water treatment, and air purification. The effectiveness of adsorption is highly dependent on the surface area of the charcoal and the properties of the gas or substance being adsorbed.

In our exercise, we are focusing on how activated charcoal adsorbs different gases, considering important characteristics like molecular weight and critical temperature. Understanding these properties can help predict which gases might be adsorbed more efficiently by activated charcoal.
Molecular Weight
Molecular weight plays a crucial role in the adsorption process. Generally, gases with higher molecular weights are more likely to be adsorbed by activated charcoal. This occurs because higher molecular weight gases have larger, more complex structures, which lead to stronger van der Waals forces.

These forces contribute to the physical attraction between the gas molecules and the surface of the activated charcoal. In the given problem, we compare different gases:
  • extbf{ extit{ ext{N}_2}}: 28 g/mol } } } }
  • extbf{ extit{ ext{CO}}: 28 g/mol } } } }
  • extbf{ extit{ ext{HCl}}: 36.46 g/mol } } } }
  • extbf{ extit{ ext{CO}_2}}: 44 g/mol } } } }
Among these, extbf{ extit{ ext{CO}_2} }} has the highest molecular weight, suggesting higher adsorption potential if only molecular weight were considered.

However, adsorption is also influenced by critical temperature, so we must consider both factors together to fully understand the adsorption capabilities of activated charcoal.
Critical Temperature
Critical temperature is the highest temperature at which a substance can exist as a liquid. Above this temperature, a gas cannot be liquefied, regardless of the pressure applied. In adsorption processes, gases with higher critical temperatures tend to have higher adsorption potentials.

This is because such gases can be more readily condensed under pressure. Therefore, understanding critical temperatures helps in predicting and enhancing the adsorption process. In our example:
  • extbf{ extit{ ext{N}_2}}: 126.2 K } } } }
  • extbf{ extit{ ext{CO}}: 132.9 K } } } }
  • extbf{ extit{ ext{HCl}}: 324.5 K } } } }
  • extbf{ extit{ ext{CO}_2}}: 304.2 K } } } }
extbf{ extit{ ext{HCl} }} has the highest critical temperature among the compared gases, which indicates a strong potential for adsorption. Higher values promote stronger interactions with activated charcoal by increasing the likelihood that the gas's molecules will interact and adhere to the charcoal's surface.

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