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Arrange the following gases in order of increasing root-mean-square speed at the same temperature: \(\mathrm{O}_{2}, \mathrm{N}_{2}, \mathrm{H}_{2} \mathrm{O}, \mathrm{CO}_{2}, \mathrm{NO}_{2},^{235} \mathrm{UF}_{6},\) and \(^{238} \mathrm{UF}_{6}\).

Short Answer

Expert verified
Order: \(^{238}\mathrm{UF}_6, ^{235}\mathrm{UF}_6, \mathrm{NO}_2, \mathrm{CO}_2, \mathrm{O}_2, \mathrm{N}_2, \mathrm{H}_2\mathrm{O}\).

Step by step solution

01

Understand Root-Mean-Square Speed

The root-mean-square speed (RMS) of a gas is given by the formula: \( v_{rms} = \sqrt{\frac{3RT}{M}} \), where \( R \) is the ideal gas constant, \( T \) is the absolute temperature, and \( M \) is the molar mass. Gases with lower molar masses have higher RMS speeds at the same temperature.
02

List Molar Masses of Gases

Identify and list the molar masses of the given gases: \(\mathrm{O}_2 = 32 \, g/mol \), \(\mathrm{N}_2 = 28 \, g/mol \), \(\mathrm{H}_2\mathrm{O} = 18 \, g/mol \), \(\mathrm{CO}_2 = 44 \, g/mol \), \(\mathrm{NO}_2 = 46 \, g/mol \), \(^{235}\mathrm{UF}_6 = 349 \, g/mol \), and \(^{238}\mathrm{UF}_6 = 352 \, g/mol \).
03

Arrange Gases by Molar Mass

Order the gases from lowest to highest molar mass. Using the molar masses: \(\mathrm{H}_2\mathrm{O} < \mathrm{N}_2 < \mathrm{O}_2 < \mathrm{CO}_2 < \mathrm{NO}_2 < ^{235}\mathrm{UF}_6 < ^{238}\mathrm{UF}_6\).
04

Determine RMS Speed Order

Since RMS speed is inversely proportional to the square root of molar mass, gases with lower molar masses have higher speeds. Therefore, at the same temperature, the order of increasing RMS speed is: \(^{238}\mathrm{UF}_6, ^{235}\mathrm{UF}_6, \mathrm{NO}_2, \mathrm{CO}_2, \mathrm{O}_2, \mathrm{N}_2, \mathrm{H}_2\mathrm{O}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molar Mass
Molar mass is a fundamental property of substances and is particularly important when discussing gases. It is defined as the mass of one mole of a substance, usually expressed in grams per mole (g/mol). The molar mass of a gas determines how much one mole of the gas weighs and plays a crucial role in various calculations, such as determining the density and volume of gases under certain conditions.
Molar mass is essential in the context of the root-mean-square speed because it influences how quickly gas particles move at a specific temperature. Specifically, lighter gases with lower molar masses tend to have higher RMS speeds, meaning they move faster than heavier gases with higher molar masses, at the same temperature.
Ideal Gas Constant
The ideal gas constant, often denoted as `R`, is a key component of the ideal gas law, a fundamental equation in chemistry and physics. Its value is approximately 8.314 J/(mol·K), which combines energy with temperature, molar quantity, and pressure into one constant.
In the RMS speed formula, the ideal gas constant serves as a link between temperature and the kinetic energy of gas particles. It ensures that the mathematical relationship between pressure, volume, temperature, and number of moles is consistent, predicting the behavior of ideal gases accurately under many conditions.
Temperature Dependence
Temperature is a critical factor that significantly affects gas behavior, including their speed and energy. In gas calculations, it is always considered in absolute terms, using Kelvin, as this measurement starts from absolute zero. Absolute zero is the lowest temperature possible, where theoretically, particles would be at rest.
For the root-mean-square speed, temperature is directly proportional to the speed of gas particles. This means as the temperature increases, so does the kinetic energy of the particles, causing them to move faster. Thus, temperature plays a crucial role in determining how quickly gas particles are moving, based on their RMS speed.
Gas Properties
Gases have unique properties that differentiate them from other states of matter like solids and liquids. These include high compressibility, low density, and the ability to fill their containers regardless of shape.
In terms of kinetic theory, gas properties are explained by the movement and collisions of tiny particles in constant motion. This motion is randomized and rapid, with particles moving in straight lines until colliding with each other or the walls of their container. These collisions, in turn, relate to properties like pressure and volume.
The properties of gases affect how we understand RMS speed. For instance, lighter gases will be more dispersed and faster, correlating with a higher RMS speed compared to heavier gases that might be denser and slower.
RMS Speed Formula
The root-mean-square speed (RMS) formula is a critical equation in the study of gases, providing insights into the motion of gas particles. The formula is represented as: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \]In this equation, \( v_{rms} \) is the root-mean-square speed, \( R \) is the ideal gas constant, \( T \) is the absolute temperature, and \( M \) is the molar mass of the gas.
This formula highlights two key relationships:
  • The speed of gas particles increases with temperature, due to the direct proportionality of temperature \( T \) in the formula.
  • The speed decreases with higher molar mass, as \( M \) appears in the denominator under a square root, indicating inverse proportionality.
Thus, RMS speed helps us predict how different gases will behave under varying conditions of temperature and mass.

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