Chapter 33: Problem 17
Demonstrate that the Maxwell-Boltzmann speed distribution is normalized.
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Chapter 33: Problem 17
Demonstrate that the Maxwell-Boltzmann speed distribution is normalized.
These are the key concepts you need to understand to accurately answer the question.
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The escape velocity from Earth's surface is given by \(\mathrm{v}_{E}=(2 g R)^{1 / 2}\) where \(g\) is the gravitational acceleration \(\left(9.807 \mathrm{m} \mathrm{s}^{-2}\right)\) and \(R\) is the radius of Earth \(\left(6.37 \times 10^{6} \mathrm{m}\right)\) a. At what temperature will \(\nu_{\mathrm{mp}}\) for \(\mathrm{N}_{2}\) be equal to the escape velocity? b. How does the answer for part (a) change if the gas of interest is He? c. What is the largest molecular mass that is capable of escaping Earth's surface at \(298 \mathrm{K} ?\)
a. How many molecules strike a \(1.00 \mathrm{cm}_{2}\) surface during 1 minute if the surface is exposed to \(\mathrm{O}_{2}\) at 1 atm and \(298 \mathrm{K} ?\) b. Ultrahigh vacuum studies typically employ pressures on the order of \(10^{-10}\) Torr. How many collisions will occur at this pressure at \(298 \mathrm{K} ?\)
a. What is the average time required for \(\mathrm{H}_{2}\) to travel \(1.00 \mathrm{m}\) at \(298 \mathrm{K}\) and 1 atm? b. How much longer does it take \(\mathrm{N}_{2}\) to travel \(1.00 \mathrm{m},\) on average, relative to \(\mathrm{H}_{2}\) under these same conditions? c. (Challenging) What fraction of \(\mathrm{N}_{2}\) particles will require more than this average time to travel \(1.00 \mathrm{m} ?\) Answering this question will require evaluating a definite integral of the speed distribution, which requires using numerical methods such as Simpson's rule.
a. The stratosphere begins at \(11 \mathrm{km}\) above Earth's surface. At this altitude \(P=22.6 \mathrm{kPa}\) and \(T=-56.5^{\circ} \mathrm{C} .\) What is the mean free path of \(\mathrm{N}_{2}\) at this altitude assuming \(\mathrm{N}_{2}\) is the only component of the stratosphere? b. The stratosphere extends to \(50.0 \mathrm{km}\) where \(P=0.085 \mathrm{kPa}\) and \(T=18.3^{\circ} \mathrm{C} .\) What is the mean free path of \(\mathrm{N}_{2}\) at this altitude?
A comparison of \(\nu_{\text {ave}}, \nu_{m p},\) and \(\nu_{r m s}\) for the Maxwell speed distribution reveals that these three quantities are not equal. Is the same true for the one-dimensional velocity distributions?
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