Chapter 2: Problem 15
What is the \(K_{\mathrm{a}}\) of HCN if its \(\mathrm{p} K_{\mathrm{a}}=9.31\) ?
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Chapter 2: Problem 15
What is the \(K_{\mathrm{a}}\) of HCN if its \(\mathrm{p} K_{\mathrm{a}}=9.31\) ?
These are the key concepts you need to understand to accurately answer the question.
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Make three-dimensional drawings of the following molecules, and predict whether each has a dipole moment. If you expect a dipole moment, show its direction. (a) \(\mathrm{H}_{2} \mathrm{C}=\mathrm{CH}_{2}\) (b) \(\mathrm{CHCl}_{3}\) (c) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\) (d) \(\mathrm{H}_{2} \mathrm{C}=\mathrm{CCl}_{2}\)
Fluoromethane \(\left(\mathrm{CH}_{3} \mathrm{~F}, \mu=1.81 \mathrm{D}\right.\) ) has a smaller dipole moment than chloromethane \(\left(\mathrm{CH}_{3} \mathrm{Cl}, \mu=1.87 \mathrm{D}\right)\), even though fluorine is more electronegative than chlorine. Explain.
The ammonium ion \(\left(\mathrm{NH}_{4}{ }^{+}, \mathrm{p} K_{\mathrm{a}}=9.25\right)\) has a lower \(\mathrm{p} K_{\mathrm{a}}\) than the methylammonium ion \(\left(\mathrm{CH}_{3} \mathrm{NH}_{3}+, \mathrm{p} K_{\mathrm{a}}=10.66\right)\). Which is the stronger base, ammonia \(\left(\mathrm{NH}_{3}\right)\) or methylamine \(\left(\mathrm{CH}_{3} \mathrm{NH}_{2}\right) ?\) Explain.
The O-H hydrogen in acetic acid is much more acidic than any of the C-H hydrogens. Explain.
Calculate formal charges for the nonhydrogen atoms in the following molecules: (a) Diazomethane, \(\mathrm{H}_{2} \mathrm{C}=\mathrm{N}=\ddot{\mathrm{N}}\) : (b) Acetonitrile oxide, \(\mathrm{H}_{3} \mathrm{C}-\mathrm{C} \equiv \mathrm{N}-\ddot{\mathrm{O}}\) : (c) Methyl isocyanide, \(\mathrm{H}_{3} \mathrm{C}-\mathrm{N} \equiv \mathrm{C}\) :
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