Chapter 3: Q49 (page 190)
Question: Draw Newman projections along the C3-C4bond to show the most stable and least stable conformations of 3 ethyl-2,4demethylheptane.
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Chapter 3: Q49 (page 190)
Question: Draw Newman projections along the C3-C4bond to show the most stable and least stable conformations of 3 ethyl-2,4demethylheptane.
Answer

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(a) Draw the two chair conformations of , and label all the positions as axial or equatorial.
(b) Label the higher-energy conformation and the lower-energy conformation.
(c) The energy difference in these two conformations has been measured to be aboutper mole. How much of this energy difference is due to the torsional energy of gauche relationships?
(d) How much energy is due to the additional steric strain of thediaxial interaction?
Draw the structure and give the molecular formula for each of the following compounds.
(a) 1-ethyl-3-methylcycloheptane
(b) isobutylcyclohexane
(c) cyclopropylcyclopentane
(d) 3-ethyl-1,1-dimethylcyclohexane
(e) 3-ethyl-2,4-dimethylhexane
(f) 1,1-diethyl-4-(3,3-dimethylbutyl)cyclohexane
Draw the structure that corresponds with each name.
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
(i)
(j)
(k)
(l)
Give IUPAC names for the following cycloalkanes.
(a)

(b)

(c)

Question: Convert each Newman projection to the equivalent line-angle formula, and assign the IUPAC name.
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