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Chapter 3: Q22P (page 176)

Draw 1,2,3,4,5,6-hexamethylcyclohexane with all the methyl groups

(a) in axial positions. (b) in equatorial positions.

Short Answer

Expert verified

(a)

(b)

Step by step solution

01

Step 1:

If we could freeze cyclohexane in a chair conformation, we would see that there are two different kinds of carbon鈥揾ydrogen bonds. Six of the bonds (one on each carbon atom) are directed up and down, parallel to the axis of the ring. These are called axial bonds. The other six bonds point out from the ring, along the 鈥渆quator鈥� of the ring. These are called equatorial bonds.

02

(a)

The axial bonds are drawn vertically to the ring connections for all methyl groups.

03

(b)

Equatorial bonds are drawn parallel to the ring connections for all methyl groups.

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Most popular questions from this chapter

Draw the structure that corresponds with each name.

(a)3-ethyloctane

(b)4-isopropyldecane

(c)sec-butylcycloheptane

(d)2,3-dimethyl-4-propylnonane

(e)2,2,4,4-tetramethylhexane

(f)trans-1,3-diethylcyclopentane

(g)cis-1-ethyl-4-methylcyclohexane

(h)isobutylcyclopentane

(i)tert-butylcyclohexane

(j)pentylcyclohexane

(k)cyclobutylcyclohexane

(l)cis-1-bromo-3-chlorocyclohexane

Question: All of the following names are incorrect or incomplete. In each case, draw the structure ( or a possible structure) and name it correctly

Question: Using the general formula for alkanes

  1. Predict the molecular formula of theC27straight chain alkane.
  2. Predict the molecular formula of the alkanes containing 42 carbon atom with extensive branching.

Question: Convert each Newman projection to the equivalent line-angle formula, and assign the IUPAC name.
  1. There are 18 isomeric alkanes of molecular formula C8H18. Draw and name any eight of them.
  2. Draw and name the six isomeric cyclopentane of molecular formula C7H14. These will include four constitutional isomers, of which two show geometric (cis-trans) stereoisomerism.
See all solutions

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