Chapter 18: Q52P (page 970)
Show how you would synthesize the following derivatives from appropriate carbonyl compounds



Short Answer
a.

b.

c.

d.

e.

f.

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Chapter 18: Q52P (page 970)
Show how you would synthesize the following derivatives from appropriate carbonyl compounds



a.

b.

c.

d.

e.

f.

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Trimethylphosphine is a stronger nucleophile than triphenylphosphine, but it is rarely used to make ylides. Why is trimethylphosphine unsuitable for making most phosphorus ylides?
PROBLEM 18-10
Predict the products of the following reactions:

is frequently used for making derivatives of ketones and aldehydes because the products (, called derivatives) are even more likely than the phenlyhydrazones to be solids with sharp melting points. Propose a mechanism for the reaction of acetone with in a mildly acidic solution.
Predict the products of the following reactions.

Show how you would accomplish the following syntheses efficiently and in good yield. You may use any necessary reagents.
(a)
(b)

(c)

(d)

(e)

(f)

(g)

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