Chapter 2: Problem 35
What is the conjugate acid of each base? a. H\(_2\)O b. \(^-\)NH\(_2\) c. HCO\(_3{^-}\) d. CH\(_3\)CH\(_2\)NHCH\(_3\) e. CH\(_3\)OCH\(_3\) f. CH\(_3\)COO\(^-\)
Short Answer
Expert verified
a. H鈧僌鈦 b. NH鈧 c. H鈧侰O鈧 d. CH鈧僀H鈧侼H鈧傗伜CH鈧 e. CH鈧僌鈦篐鈧侰H鈧 f. CH鈧僀OOH
Step by step solution
01
Understanding Conjugate Acid Formation
To find the conjugate acid of a base, we need to add a proton (H鈦) to the base. This is because the conjugate acid of a base has one more proton than the base.
02
Finding the Conjugate Acid of H2O
Water, H鈧侽, acts as a base when it gains a proton. Adding a proton, we get H鈧僌鈦, which is known as the hydronium ion. Thus, the conjugate acid of H鈧侽 is H鈧僌鈦.
03
Finding the Conjugate Acid of NH2^-
The amide ion, NH鈧傗伝, will gain a proton to form NH鈧. Therefore, the conjugate acid of NH鈧傗伝 is NH鈧.
04
Finding the Conjugate Acid of HCO3^-
The bicarbonate ion, HCO鈧冣伝, will gain a proton to become H鈧侰O鈧, carbonic acid. So, the conjugate acid of HCO鈧冣伝 is H鈧侰O鈧.
05
Finding the Conjugate Acid of CH3CH2NHCH3
Dimethylethylamine, CH鈧僀H鈧侼HCH鈧, acts as a base. Adding a proton to the nitrogen atom, we get CH鈧僀H鈧侼H鈧傗伜CH鈧. Thus, the conjugate acid is CH鈧僀H鈧侼H鈧傗伜CH鈧.
06
Finding the Conjugate Acid of CH3OCH3
Dimethyl ether, CH鈧僌CH鈧, when gaining a proton, attaches the proton to the oxygen. This forms CH鈧僌鈦篐鈧侰H鈧. Therefore, the conjugate acid is CH鈧僌鈦篐鈧侰H鈧.
07
Finding the Conjugate Acid of CH3COO^-
The acetate ion, CH鈧僀OO鈦, gains a proton to form acetic acid, CH鈧僀OOH. Thus, the conjugate acid of CH鈧僀OO鈦 is CH鈧僀OOH.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Organic Chemistry
Organic chemistry is a vast field that studies carbon-containing compounds. These compounds are unique for their covalent bonding and structural diversity, including chains and rings. In organic chemistry, understanding how molecules interact, specifically through reactions, is crucial.
One essential part of organic chemistry involves the study of functional groups. These groups, such as amines, alcohols, and ethers, are characteristic arrangements of atoms that give organic molecules specific properties. For instance, the amine group (NH鈧) is known for being a base, due to its ability to attract protons.
One essential part of organic chemistry involves the study of functional groups. These groups, such as amines, alcohols, and ethers, are characteristic arrangements of atoms that give organic molecules specific properties. For instance, the amine group (NH鈧) is known for being a base, due to its ability to attract protons.
- Amines: Contains a nitrogen atom with a lone pair that can accept protons.
- Alcohols: Characterized by the presence of an -OH group.
- Ethers: Have an oxygen atom connected to two alkyl or aryl groups.
Acid-Base Reactions
Acid-base reactions are fundamental in understanding chemical interactions. They involve the transfer of protons (H鈦 ions) between reactants. This step is crucial for identifying conjugate acids and bases.
These reactions are defined by the Bronsted-Lowry theory, which states:
Moreover, acid-base reactions are imperative in regulating pH levels, creating buffers, and understanding biological processes like enzyme function. By mastering this concept, one can appreciate how different substances interact at the molecular level.
These reactions are defined by the Bronsted-Lowry theory, which states:
- Acids donate protons (H鈦 ions).
- Bases accept protons (H鈦 ions).
Moreover, acid-base reactions are imperative in regulating pH levels, creating buffers, and understanding biological processes like enzyme function. By mastering this concept, one can appreciate how different substances interact at the molecular level.
Conjugate Acid-Base Pairs
Conjugate acid-base pairs are essential for grasping acid-base reactions. A conjugate pair consists of two species that transform into each other by gaining or losing a proton. When a base gains a proton, it turns into its conjugate acid, and vice versa.
Here鈥檚 how conjugate acid-base pairs work:
The strength of acids and bases in these pairs varies. A strong acid has a weak conjugate base, while a strong base has a weak conjugate acid. Understanding this relationship aids in assessing reaction spontaneity and guiding synthetic pathways in organic chemistry.
Here鈥檚 how conjugate acid-base pairs work:
- H鈧侽 as a base forms H鈧僌鈦, its conjugate acid.
- NH鈧傗伝 gains a proton to form NH鈧, its conjugate acid.
- CH鈧僀OO鈦 becomes CH鈧僀OOH upon protonation, its conjugate acid.
The strength of acids and bases in these pairs varies. A strong acid has a weak conjugate base, while a strong base has a weak conjugate acid. Understanding this relationship aids in assessing reaction spontaneity and guiding synthetic pathways in organic chemistry.