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The defect when an ion occupies an interstitial position in the crystal lattice is called: (a) Schottky defect (b) Crystal defect (c) Frenkel defect (d) None of these

Short Answer

Expert verified
The correct answer is option (c) Frenkel defect.

Step by step solution

01

Understanding the Defect Types

There are various types of point defects in crystals. A Schottky defect occurs when an atom or ion is missing from the lattice, creating a vacancy. A Frenkel defect (also known as a dislocation defect) occurs when an ion leaves its proper place in the lattice and occupies an interstitial site, which is an abnormal position within the lattice structure.
02

Comparing the Options with the Definition

Now compare the given options with the definition of Frenkel defect. A Frenkel defect is indeed the scenario when an ion occupies an interstitial site in the lattice. Hence, among the given options, the correct one must align with this condition.
03

Identifying the Correct Option

Since the Frenkel defect matches the condition described in the exercise, where an ion is in an interstitial position, the correct answer is therefore option (c) Frenkel defect.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Crystal Lattice Defects
Crystal lattice defects are disruptions in the orderly pattern of a crystal's structure. In an ideal crystal, atoms or ions are arranged in a repeating pattern, extending in all three spatial dimensions. However, in reality, no crystal is perfect; defects invariably occur and these imperfections can significantly affect the physical and chemical properties of the material, including electrical conductivity, optical clarity, and mechanical strength.

There are several types of defects that can occur within a crystal structure. These include point defects, which involve a single or a small cluster of atoms; line defects, which pertain to discrepancies along a line in the crystal; and planar defects, which occur across a two-dimensional plane within the crystal. These imperfections are not mere anomalies but can be integral to the functionality of materials in various applications, such as semiconductors and ceramics.
Schottky Defect
In the context of point defects, the Schottky defect is a vacancy defect occurring in compound crystals, such as ionic crystals. This defect involves equal numbers of cations and anions leaving their lattice sites, thereby maintaining electrical neutrality. The evacuated sites are known as vacancies.

The presence of Schottky defects has implications on the density and ionic conductivity of the material. Since atoms are missing from the crystal lattice, the density of the crystal decreases. These defects are predominant in compounds with high coordination numbers and where ions have similar sizes. A typical example of a material exhibiting Schottky defects is sodium chloride (NaCl), where approximately one out of every million sodium ions is missing from its lattice site.
Point Defects in Crystals
Point defects in crystals are imperfections at the atomic or ionic scale that disrupt the ideal periodic arrangement within a crystal lattice. These can be viewed as 'mistakes' in the otherwise orderly pattern of atoms. They are categorized into different types, such as vacancies, interstitials, and substitutional atoms or ions. Each type of point defect carries distinct characteristics and results in different property alterations of the crystal.

Vacancies are points where an atom is missing, interstitials occur when atoms occupy spaces between the regular lattice sites, and substitutional defects happen when a foreign atom replaces a host lattice atom. The behavior and concentration of point defects can be influenced by factors such as temperature, with higher temperatures generally increasing the number of point defects due to increased atomic mobility. In the case of point defects, like the Frenkel defect, it involves an atom or ion vacating its lattice position to occupy an interstitial site. This can lead to increased ionic conductivity as the presence of these defects provides a pathway for ions to move through the lattice.

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Most popular questions from this chapter

In a compound, atoms of element \(\mathrm{Y}\) from ccp lattice and those of element \(\mathrm{X}\) occupy \(2 / 3^{\text {nd }}\) of tetrahedral voids. The formula of the compound will be: (a) \(\mathrm{X}_{4} \mathrm{Y}_{3}\) (b) \(\mathrm{X}_{2} \mathrm{Y}_{3}\) (c) \(\mathrm{X}_{2} \mathrm{Y}\) (d) \(\mathrm{X}_{3} \mathrm{Y}_{4}\)

The closet distance between two atoms (in terms of edge length) would be highest for which of unit cell, assuming the edge length of each unit cell of be 'a':(a) FCC unit cell (b) \(\mathrm{BCC}\) unit cell (c) Diamond unit cell (d) Primitive cubic cell

A substance \(\mathrm{A}_{\mathrm{x}} \mathrm{B}_{\mathrm{y}}\) crystallizes in a face-centred cubic (FCC) lattice in which atoms 'A' occupy each corner of the cube and atoms 'B' occupy the centres of each face of the cube. Identify the correct composition of the substance \(\mathrm{A}_{\mathrm{x}} \mathrm{B}_{\mathrm{y}}\) (a) \(\mathrm{AB}_{3}\) (b) \(\mathrm{A}_{4} \mathrm{~B}_{3}\) (c) \(\mathrm{A}_{3} \mathrm{~B}\) (d) Composition cannot be specified

An example of a ferromagnetic oxide is: (a) \(\mathrm{TiO}_{2}\) (b) \(\mathrm{CrO}_{2}\) (c) \(\mathrm{Mn}_{2} \mathrm{O}_{7}\) (d) \(\mathrm{Fe}_{3} \mathrm{O}_{4}\)

The intercepts made by a plane along the \(\mathrm{X}, \mathrm{Y}\) and \(\mathrm{Z}\) axes are respectively \(2 \mathrm{a}, 2 \mathrm{~b}\) and \(\infty \mathrm{c}\) where \(\mathrm{a}, \mathrm{b}\) and \(\mathrm{c}\) are the respective unit distances along these axes. The Miller indices of the plane are: (a) \(1,1,0\) (b) \(0,2,2\) (c) \(2,2, \infty\) (d) \(1,1, \infty\)

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