Chapter 11: Problem 49
The IUPAC name of the compound \(\mathrm{CH}_{3}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{2}-\mathrm{CH}=\mathrm{C}\left(\mathrm{CH}_{3}\right)_{2}\) is (a) \(1,1,3,3\) -tetramethyl-but-1-ene (b) \(1,3,3\) -trimethyl-pent-2-ene (c) \(2,2,4\) -trimethylbut- 4 -ene (d) \(2,4,4\) -trimethylpent- 2 -ene
Short Answer
Step by step solution
Identify the Longest Carbon Chain
Number the Carbon Chain
Identify and Name the Substituents
Assemble the IUPAC Name
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Organic Chemistry
One of the most interesting aspects of organic chemistry is the vast diversity of compounds that carbon can create. Understanding these compounds involves studying their structural formulas and learning principles to identify and name them accurately. Such skills are critical in helping chemists communicate chemical compositions and reactions succinctly and clearly.
Chemical Structure Identification
When we look at a chemical structure, like the one in the exercise, we see a pattern of atoms and bonds. Each carbon atom has a specific number of bonds, typically four, due to its tetravalency. The position of these bonds, particularly in relation to double bonds or functional groups, helps us determine its chemical behavior and how it interacts with other molecules.
Remember, chemical structure identification isn't just about spotting features. It's about understanding how those features dictate the compound's properties and reactivity.
Alkene Naming
In IUPAC nomenclature, alkenes have the suffix "-ene," indicating a double bond. The position of this bond is crucial and should be identified when numbering the carbon chain. Begin numbering from the end nearest to the double bond to assign the lowest possible number to the bond's location. In our exercise, the double bond in the compound begins at carbon 2, leading to the "pent-2-ene" portion of the name.
Correctly naming alkenes ensures clear communication of their structure and potential chemical reactions.
Longest Carbon Chain
In the given exercise, the longest chain containing the double bond has five carbon atoms, which corresponds to the root name "pent". This chain must be chosen to include the double bond, providing the main structural characteristic of the molecule.
Remember, accurately identifying the longest chain helps in systematically naming complex organic structures, allowing for an organized and predictable method of chemical classification.
Substituents Naming
Methyl groups, indicated by the chemical formula CH extsubscript{3}, are common substituents in organic frameworks. In our exercise, three methyl groups are present, two on carbon 3 and one on carbon 2. This leads to the "2,4,4-trimethyl" segment of the compound's name.
Substituents increase the complexity of the molecule's structure and function, making it imperative to follow IUPAC rules to assign their numbers and names correctly. This ensures the clarity and consistency necessary for chemical communication.