Chapter 10: Problem 122
A colourless poisonous gas (A) burns with blue flame is passed through aqueous \(\mathrm{NaOH}\) at high pressure and temperature to give a compound (B). (B) on heating gives (C) and (C) gives white precipitate (D) with \(\mathrm{CaCl}_{2}\) both (C) and (D) decolourise acidified \(\mathrm{KMnO}_{4}\). Here (A) can be: (a) \(\mathrm{CO}\) (b) \(\mathrm{CO}_{2}\) (c) \(\mathrm{SO}\), (d) \(\mathrm{H}_{2} \mathrm{~S}\)
Short Answer
Step by step solution
Identify the Gas
React with Aqueous NaOH
Determine the Compound after Heating
React with CaCl2
Decolourising Acidified KMnO4
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Gas Reactions
- Combustion, as seen with \ ext{CO}, is a common gas reaction.
- Gas reactions can lead to the formation of precipitates or new compounds.
- They often require controlled environments to ensure safety and product yield.
Carbon Monoxide
- CO is dangerous because it binds to hemoglobin, reducing oxygen transport in the body.
- Despite its toxicity, it is useful in applications requiring a reducing atmosphere or synthesis of certain chemicals.
- Proper ventilation and detectors are essential when working with or near CO, especially in industrial environments.
Chemical Analysis
- Techniques include both qualitative and quantitative analysis.
- Chemical tests often involve reactions leading to visible changes, such as color or precipitate formation.
- Instrumental methods like spectroscopy can provide detailed insights into compound structures and interactions.
Precipitation Reactions
- Precipitation reactions are driven by the insolubility of the product in water.
- The appearance of a solid indicates a chemical change has occurred.
- These reactions have practical applications, from manufacturing to environmental science.