Chapter 1: Problem 52
Which of the following mixtures contain less number of ions? (1) \(2 \mathrm{M} \mathrm{K}_{2} \mathrm{SO}_{4} ; 3 \mathrm{M} \mathrm{Na}_{2} \mathrm{CO}_{3}\) (2) \(2 \mathrm{M} \mathrm{NaC} 1 ; 2 \mathrm{M} \mathrm{KC} 1\) (3) \(2 \mathrm{M} \mathrm{MnSO}_{4} ; 2 \mathrm{M} \mathrm{K}_{2} \mathrm{SO}_{4}\) (4) \(2 \mathrm{M} \mathrm{K}_{2} \mathrm{SO}_{4} ; 2 \mathrm{M}\left(\mathrm{NII}_{4}\right)_{2} \mathrm{SO}_{4}\)
Short Answer
Step by step solution
- List the components for each mixture
- Dissociate each compound into ions
- Calculate the total number of ions for each mixture
- Compare the total number of ions for each mixture
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Compounds
Sodium chloride is a simple ionic compound, but there are many others with more complex structures.
- Common ionic compounds include salts, such as potassium sulfate (K鈧係O鈧) and ammonium sulfate ((NH鈧)鈧係O鈧).
- The structure of ionic compounds usually forms a crystalline lattice which minimizes the potential energy of the system.
Dissociation Equations
\[ \text{NaCl} \rightarrow \text{Na}^+ + \text{Cl}^- \]
Each dissociation equation shows what ions are produced from one formula unit of the ionic compound in water.
- For potassium sulfate (K鈧係O鈧): \[ \text{K}_2\text{SO}_4 \rightarrow 2\text{K}^+ + \text{SO}_4^{2-} \]
- For ammonium sulfate ((NH鈧)鈧係O鈧): \[ (\text{NH}_4)_2\text{SO}_4 \rightarrow 2\text{NH}_4^+ + \text{SO}_4^{2-} \]
Molarity
\[ \text{Molarity} = \frac{\text{moles of solute}}{\text{liters of solution}} \]
For example, a 2 M solution of potassium sulfate (K鈧係O鈧) means there are 2 moles of K鈧係O鈧 dissolved in 1 liter of solution. Molarity is important because it helps quantify the concentration of ions in a solution after dissociation. When calculating how many ions are in a solution, you need to know the molarity of the original solution.
In a problem that involves comparing ion concentrations, knowing the molarity of each component helps determine which mixture has more or fewer ions. For instance, if you have 2 M K鈧係O鈧 and 3 M Na鈧侰O鈧, the molarity tells you how many ions form when each dissolves.
- 2 M K鈧係O鈧 produces 2 K鈦 and 1 SO鈧劼测伝, hence producing 6 ions for the 2 moles total.
- 3 M Na鈧侰O鈧 produces 2 Na鈦 and 1 CO鈧兟测伝 for each formula unit, leading to a total of 9 ions from 3 moles.
Ion Counting
First, write the dissociation equation for each compound in the solution. Then, use the molarity to determine how many moles of each ion are produced. Finally, sum up the ions.
Here's an example:
- For 2 M K鈧係O鈧:\[ \text{K}_2\text{SO}_4 \rightarrow 2\text{K}^+ + \text{SO}_4^{2-} \]Each mole of K鈧係O鈧 produces 3 ions (2 K鈦 and 1 SO鈧劼测伝). So, 2 M K鈧係O鈧 gives 6 ions total.
- For 3 M Na鈧侰O鈧:\[ \text{Na}_2\text{CO}_3 \rightarrow 2\text{Na}^+ + \text{CO}_3^{2-} \] Each mole of Na鈧侰O鈧 produces 3 ions, giving us 9 ions total.