Chapter 3: Problem 56
$$ \text { Write electronic configuration of } \mathrm{Fe}^{2+}, \mathrm{Mn}^{4+}, \mathrm{N}^{3-} \text { and } \mathrm{O}^{2-} \text { ions. } $$
Short Answer
Expert verified
Fe虏鈦: [Ar] 3d鈦; Mn鈦粹伜: [Ar] 3d鲁; N鲁鈦: 1s虏 2s虏 2p鈦; O虏鈦: 1s虏 2s虏 2p鈦.
Step by step solution
01
Determine the number of electrons in Fe虏鈦
Iron (Fe) has an atomic number of 26, which means its neutral atom has 26 electrons. As a cation with a 2+ charge, Fe虏鈦 has lost two electrons. Therefore, Fe虏鈦 has 24 electrons.
02
Write the electron configuration of Fe虏鈦
The electron configuration of a neutral iron atom is [Ar] 3d鈦 4s虏. For Fe虏鈦, we remove two electrons from the 4s orbital first, giving [Ar] 3d鈦.
03
Determine the number of electrons in Mn鈦粹伜
Manganese (Mn) has an atomic number of 25, meaning its neutral atom has 25 electrons. As a cation with a 4+ charge, Mn鈦粹伜 has lost four electrons. Therefore, Mn鈦粹伜 has 21 electrons.
04
Write the electron configuration of Mn鈦粹伜
The electron configuration of a neutral manganese atom is [Ar] 3d鈦 4s虏. For Mn鈦粹伜, we remove two electrons from the 4s orbital and two from the 3d orbital, giving [Ar] 3d鲁.
05
Determine the number of electrons in N鲁鈦
Nitrogen (N) has an atomic number of 7, which means its neutral atom has 7 electrons. As an anion with a 3- charge, N鲁鈦 has gained three electrons. Therefore, N鲁鈦 has 10 electrons.
06
Write the electron configuration of N鲁鈦
The electron configuration of a neutral nitrogen atom is 1s虏 2s虏 2p鲁. For N鲁鈦, we added three electrons to the 2p orbital, which gives the electron configuration: 1s虏 2s虏 2p鈦.
07
Determine the number of electrons in O虏鈦
Oxygen (O) has an atomic number of 8, meaning its neutral atom has 8 electrons. As an anion with a 2- charge, O虏鈦 has gained two electrons. Therefore, O虏鈦 has 10 electrons.
08
Write the electron configuration of O虏鈦
The electron configuration of a neutral oxygen atom is 1s虏 2s虏 2p鈦. For O虏鈦, we add two electrons to the 2p orbital, which gives the electron configuration: 1s虏 2s虏 2p鈦.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation States
Oxidation states, also known as oxidation numbers, are a method used in chemistry to keep track of electrons in atoms, molecules, and ions. Particularly, they tell us how many electrons an atom has lost, gained, or shared when forming a bond or becoming an ionic species. For instance, in the exercise, iron loses two electrons to become Fe虏鈦, indicating it has an oxidation state of +2. Similarly, manganese loses four electrons to form Mn鈦粹伜, giving it an oxidation state of +4. On the flip side, nitrogen gains three electrons to become N鲁鈦, reflecting an oxidation state of -3, and oxygen gains two electrons resulting in O虏鈦, which has an oxidation state of -2. Understanding oxidation states is key to predicting the chemical behavior of elements in reactions and forming compounds.
Atomic Structure
Atomic structure refers to the organization of electrons around the nucleus of an atom. Elements are defined by the number of protons in their nucleus, known as the atomic number. Electrons, which have a negative charge, are found in areas called orbitals around the nucleus. In our exercise, we looked at the atomic structure of Fe, Mn, N, and O. The electron configuration of these atoms changes when they gain or lose electrons. For example, Fe in its neutral state has 26 electrons, but as Fe虏鈦 it has only 24. Understanding the atomic structure, including the order in which orbitals are filled, is critical for determining the electron configuration of atoms and ions. It's the first step in predicting how an element will bond with others.
Transition Metals
Transition metals, such as iron and manganese in our exercise, are elements that have partially filled d-orbitals. They are located in the middle of the periodic table and are known for their ability to exhibit a variety of oxidation states. This is because the energy levels of the 3d and 4s orbitals are very close, so both can be involved in losing or gaining electrons. Transition metals are also known for forming colorful compounds and for being good conductors of electricity. Understanding how to write the electron configuration for these metals, especially after they form ions, is essential for understanding their chemistry and the types of compounds they can form.
Ionic Species
Ionic species are atoms or molecules that have a net positive or negative charge due to the loss or gain of one or more electrons. In our exercise, Fe虏鈦 and Mn鈦粹伜 are cations (positively charged ions) because they have lost electrons, whereas N鲁鈦 and O虏鈦 are anions (negatively charged ions) because they have gained electrons. The electron configurations of ionic species are critical because they determine the chemical reactivity and the type of bonds the ions can form. In solid form, ionic species constitute ionic compounds, such as salts, which have strong electrostatic attractions between the positively and negatively charged ions.