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Confirm that the completeness relation, eqn 1.25, may be expressed in terms of wavefunctions as \\[ \sum_{n} \psi_{n}(r) \psi_{n}^{*}\left(r^{\prime}\right)=\delta\left(r-r^{\prime}\right) \\] where \(\delta\left(r-r^{\prime}\right)\) is the Dirac \(\delta\) -function described in Section 2.1

Short Answer

Expert verified
The provided expression indeed represents the completeness of wavefunctions. The sum of the multiplication of a wavefunction and its complex conjugate over all states equals to the Dirac delta function, and this confirms the completeness relation.

Step by step solution

01

Understand the meaning of the equation

The given equation signifies the completeness relation in terms of wavefunctions, where \(\psi_{n}(r)\) represents the wavefunction and \(\delta\left(r-r^{\prime}\right)\) is the impulse function or Dirac delta function. This equation essentially says that the addition of all possible states (represented by n) multiplied by their complex conjugate is equal to the Dirac delta function.
02

Understand the properties of the Dirac delta function

The Dirac \(\delta\) function, \(\delta\left(r-r^{\prime}\right)\), is a function that is zero everywhere except at \(r= r'\) and its integral over the whole space is equal to 1. It's often used to represent a 'point source' or 'sink' in equations.
03

Check the Completeness

The expression is an example of the 'completeness relation', a central principle in quantum physics. A set of functions is 'complete' if any function can be written as a (possibly infinite) sum of functions from the set. For the given expression, it's assuming that the states \(\psi_{n}\) form a complete set, because when you sum over all of them and multiply by their complex conjugate, you get a Dirac delta function. It means any other function can be written as a sum of these functions. This is equivalent to the completeness of the wave functions.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Wavefunctions
In quantum mechanics, wavefunctions are mathematical descriptions of the quantum state of a system. They are central to understanding the behavior of particles at a microscopic level. A wavefunction, often denoted by \( \psi \), provides information about the probability of finding a particle at a particular position at a given time.

Understanding a wavefunction involves interpreting its magnitude and phase. The magnitude, or absolute value squared \( |\psi(r)|^2 \), represents the probability density of the particle’s position. This means it tells us where the particle is most likely to be found when measured. The phase relates to the quantum coherence and interference properties of the wave.
  • Wavefunctions can be real or complex-valued functions.
  • They must satisfy the normalization condition, meaning the total probability across all space must equal one.
  • Wavefunctions often change over time, governed by the Schrödinger equation.
Wavefunctions reflect the probabilistic nature of quantum particles, differentiating them from classical particles, which have definite positions and velocities.
Dirac Delta Function
The Dirac delta function \( \delta(r-r') \) is a special type of function that acts like a "spike" or "impulse" at a specific point. It is not a function in the traditional sense, but rather a distribution or a generalized function, used frequently in physics and engineering.

Mathematically, the Dirac delta function has distinct properties:
  • \( \delta(x) = 0 \) for all \( x eq 0 \).
  • The integral \( \int_{-\infty}^{\infty} \delta(x) \, dx = 1 \), which implies its total area under the curve is one, focusing all its values at a single point.
  • It is useful in equations to "pick out" or isolate a function's value at a particular point.
In quantum mechanics, it is critical in expressing the idea of completeness, as seen in the equation. Here, the Dirac delta function ensures that when summing over all wavefunctions, they can fully describe any position, thereby highlighting their completeness.
Quantum Mechanics
Quantum mechanics is the branch of physics that studies the behavior of particles on the atomic and subatomic level. It is a fundamental theory in physics that replaces classical mechanics in these realms.

Key principles of quantum mechanics include:
  • Wave-Particle Duality: Particles exhibit both wave-like and particle-like properties, and the nature depends on the observation.
  • Uncertainty Principle: There is a fundamental limit to the precision with which certain pairs of physical properties, such as position and momentum, can be known simultaneously (Heisenberg's Uncertainty Principle).
  • Superposition: Quantum states can exist in multiple states or configurations simultaneously until measured or observed.
In quantum mechanics, the concept of completeness of states, expressed through the completeness relation, is essential. It ensures that a quantum system can be described completely by its wavefunctions. This underpins many quantum phenomena and aids in the development of technologies such as quantum computing and quantum cryptography.

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Most popular questions from this chapter

For a particle in a box, the mean value and mean square value of the linear momentum are given by \(\int_{0}^{L} \psi^{*} p \psi \mathrm{d} x\) and \(\int_{0}^{L} \psi^{*} p^{2} \psi \mathrm{d} x,\) respectively. Evaluate these quantities. Form the root mean square deviation \(\Delta p=\left\\{\left\langle p^{2}\right\rangle-\langle p\rangle^{2}\right\\}^{1 / 2}\) and investigate the consistency of the outcome with the uncertainty principle. Hint. Use \(p=(\hbar / \mathrm{i}) \mathrm{d} / \mathrm{d} x .\) For \(\left\langle p^{2}\right\rangle\) notice that \(E=p^{2} / 2 m\) and we already know \(E\) for each \(n\). For the last part, form \(\Delta x \Delta p\) and show that \(\Delta x \Delta p \geq \frac{1}{2} \hbar,\) the precise form of the principle, for all \(n\) evaluate \(\Delta x \Delta p\) for \(n=1.\)

Calculate the energies and wavefunctions for a particle in a one-dimensional square well in which the potential energy rises to a finite value \(V\) at each end, and is zero inside the well; that is \\[ \begin{array}{ll} V(x)=V & x \leq 0 \text { and } x \geq L \\ V(x)=0 & 0

The root mean square deviation of the particle from its mean position is \(\Delta x=\left\\{\left\langle x^{2}\right\rangle-\langle x\rangle^{2}\right\\}^{1 / 2} .\) Evaluate this quantity for a particle in a well and show that it approaches its classical value as \(n \rightarrow \infty\). Hint. Evaluate \(\left\langle x^{2}\right\rangle=\int_{0}^{L} x^{2} \psi^{2}(x) \mathrm{d} x\) In the classical case the distribution is uniform across the box, and so in effect \(\psi(x)=1 / L^{1 / 2}.\)

Determine the probability of finding the ground-state harmonic oscillator stretched to a displacement beyond the classical turning point. Hint. Relate the expression for the probability to the error function, erf \(z,\) defined as \\[ \operatorname{erf} z=1-\frac{2}{\pi^{1 / 2}} \int_{z}^{\infty} \mathrm{e}^{-y^{2}} \mathrm{d} y \\] and evaluate it using erf \(1=0.8427 .\) The error function is incorporated into most mathematical software packages.

A very simple model of a polyene is the free electron molecular orbital (FEMO) model. Regard a chain of \(N\) conjugated carbon atoms, bond length \(R_{\mathrm{CC}},\) as forming a box of length \(L=(N-1) R_{\mathrm{CC}} .\) Find an expression for the allowed energies. Suppose that the electrons enter the states in pairs so that the lowest \(\frac{1}{2} N\) states are occupied. Estimate the wavelength of the lowest energy transition, taking \(R_{\mathrm{CC}}=140 \mathrm{pm}\) and \(N=22 .\) Repeat the calculation of the wavelength if the length of the chain is taken to be \((N+1) R_{\mathrm{CC}}(\) an assumption that allows for electrons to spill over the ends slightly.

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