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Which of the following bases is the weakest? \(\begin{array}{ll}\text { (A) } & \text { KOH }\end{array}\) (B) \(\mathrm{NH}_{3}\) (C) \(\mathrm{CH}_{3} \mathrm{NH}_{2}\) (D) \(\mathrm{Ca}(\mathrm{OH})_{2}\)

Short Answer

Expert verified
The weakest base is NH鈧.

Step by step solution

01

- Identify the Strong Bases

Examine the given options for strong bases. KOH (Option A) and Ca(OH)鈧 (Option D) are strong bases typically associated with Group 1 and Group 2 elements in the periodic table.
02

- Identify the Weak Bases

Identify the bases that are weaker. NH鈧 (Option B) is ammonia, and CH鈧僋H鈧 (Option C) is methylamine. Both are weak bases compared to KOH and Ca(OH)鈧.
03

- Compare Weak Bases

Compare the basicities of ammonia (NH鈧) and methylamine (CH鈧僋H鈧). CH鈧僋H鈧 is a stronger base than NH鈧 due to the +I effect of the -CH鈧 group, which increases electron density on the nitrogen.
04

- Conclude the Weakest Base

Since NH鈧 has no electron-donating group to increase its basicity, it is weaker than CH鈧僋H鈧.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Strong Bases
Strong bases are compounds that completely dissociate in water, releasing hydroxide ions (OH鈦). This full dissociation results in a high pH and a strong basicity. Examples include:
KOH (potassium hydroxide): It is a strong base because it dissociates entirely in water, forming K鈦 and OH鈦 ions.
Ca(OH)鈧 (calcium hydroxide): This is another strong base that dissociates completely into Ca虏鈦 and OH鈦 ions.
Both of these bases are members of either Group 1 or Group 2 of the periodic table, which is typical for strong bases. Remember, strong bases are highly reactive and should be handled with care.
Weak Bases
Weak bases only partially ionize in water, which means they release fewer hydroxide ions (OH鈦) compared to strong bases. This results in a lower pH compared to a solution of a strong base of the same concentration. Examples include:
NH鈧 (ammonia): This weak base does not fully dissociate in water. Instead, it forms ammonium ions (NH鈧勨伜) and hydroxide ions (OH鈦) in a reversible reaction.
CH鈧僋H鈧 (methylamine): Methylamine is slightly stronger than ammonia because the methyl group (CH鈧) donates electron density to the nitrogen, enhancing its ability to release hydroxide ions. As weak bases do not completely dissociate, their basicity is often less than that of strong bases.
Ammonia Basicity
Ammonia (NH鈧) is a common weak base. It has a lone pair of electrons on the nitrogen atom, which can accept a proton (H鈦) from water, forming ammonium (NH鈧勨伜) and hydroxide ions (OH鈦). Here's why ammonia is a weak base:
Partial ionization: Ammonia does not fully dissociate in water. Instead, it establishes an equilibrium between NH鈧, NH鈧勨伜, and OH鈦.
Lack of electron-donating groups: Unlike methylamine, ammonia lacks additional groups that could increase its basicity by donating electrons. This makes it less basic than methylamine.
Consequently, in the comparison of bases, ammonia (NH鈧) is identified as the weakest base. For students struggling with these concepts, remember that the key distinguishing feature of weak bases is their partial ionization and equilibrium in water.

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