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What \(\mathrm{H}^{+}\) concentration would you expect for the solutions below? $$ \begin{array}{ll}{\text { a. } \mathrm{pH}=9} & {\text { b. } \mathrm{pH}=7.3} \\\ {\text { c. } \mathrm{pH}=2.9} & {\text { d. } \mathrm{pH}=10.2}\end{array} $$

Short Answer

Expert verified
a. \(1 \times 10^{-9} \text{ M}\); b. \(5.01 \times 10^{-8} \text{ M}\); c. \(1.26 \times 10^{-3} \text{ M}\); d. \(6.31 \times 10^{-11} \text{ M}\).

Step by step solution

01

Understanding the Relationship Between pH and [H鈦篯

The pH of a solution is related to the hydrogen ion concentration [H鈦篯 through the equation: \[ \text{pH} = -\log[\mathrm{H}^+] \]. This means that the concentration of hydrogen ions can be calculated by rearranging this equation: \[ [\mathrm{H}^+] = 10^{-\text{pH}} \].
02

Calculate [H鈦篯 for pH = 9

For \( \text{pH} = 9 \), use the formula \( [\mathrm{H}^+] = 10^{-9} \). The concentration of hydrogen ions is \( [\mathrm{H}^+] = 1 \times 10^{-9} \text{ M} \).
03

Calculate [H鈦篯 for pH = 7.3

For \( \text{pH} = 7.3 \), use the formula \( [\mathrm{H}^+] = 10^{-7.3} \). The concentration of hydrogen ions is \( [\mathrm{H}^+] \approx 5.01 \times 10^{-8} \text{ M} \).
04

Calculate [H鈦篯 for pH = 2.9

For \( \text{pH} = 2.9 \), use the formula \( [\mathrm{H}^+] = 10^{-2.9} \). The concentration of hydrogen ions is \( [\mathrm{H}^+] \approx 1.26 \times 10^{-3} \text{ M} \).
05

Calculate [H鈦篯 for pH = 10.2

For \( \text{pH} = 10.2 \), use the formula \( [\mathrm{H}^+] = 10^{-10.2} \). The concentration of hydrogen ions is \( [\mathrm{H}^+] \approx 6.31 \times 10^{-11} \text{ M} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

pH calculation
The calculation of pH is central to understanding the acidity or basicity of any solution. Simply put, the pH scale is a measure that tells you how many hydrogen ions ([H鈦篯) are present in a solution. You can calculate pH by using the formula: \[ \text{pH} = -\log [\mathrm{H}^+] \]. This means that if you know the concentration of hydrogen ions, you can find the pH by taking the negative logarithm (base 10) of that concentration. For instance, if your [H鈦篯 is \(1 \times 10^{-7}\) M, then your pH is 7.

To reverse this, if you're given a pH, you can find [H鈦篯 using the rearranged formula: \[ [\mathrm{H}^+] = 10^{-\text{pH}} \]. This is particularly handy when solving problems where you have to determine hydrogen ion concentrations from a given pH, much like in the exercises above.

  • Keeps calculations easy and straightforward.
  • Directly connect pH values with hydrogen ion concentrations.
Hydrogen ion concentration
Hydrogen ion concentration, denoted as [H鈦篯, is pivotal in determining the acidity of a solution. The presence and amount of hydrogen ions decide how acidic or basic a solution is. If [H鈦篯 is higher, the solution is more acidic; if lower, the solution is more basic.
Measured in moles per liter, [H鈦篯 reflects the number of hydrogen ions in a given volume of solution. Focusing on the specifics, each unit change in pH translates to a tenfold change in [H鈦篯. For example, a pH drop from 7 to 6 signals a tenfold increase in hydrogen ion concentration.
Calculating [H鈦篯 is crucial in chemistry and can help predict how substances will interact with one another:
  • Acidity increases as [H鈦篯 rises
  • Lower [H鈦篯 results in basic or neutral solutions
  • Changes in [H鈦篯 affect chemical reactions and equilibria
Understanding these interactions with [H鈦篯 helps chemists manipulate and control reactions effectively.
Acid-base chemistry
Acid-base chemistry is the study of how acids and bases interact. Central to this area is the concentration of hydrogen ions [H鈦篯 and hydroxide ions [OH鈦籡. Acids are characterized by their ability to release [H鈦篯 ions, while bases typically accept these ions.
Solutions with high [H鈦篯 are acidic, whereas those with more [OH鈦籡 are basic. In neutral solutions, like pure water, the concentrations of [H鈦篯 and [OH鈦籡 are equal, giving a pH of 7.
This balance, however, can shift when an acid or base is introduced. Knowing how to work with the concepts of acids and bases becomes essential when you wish to:
  • Predict reaction outcomes
  • Balance chemical equations
  • Understand titration and buffer solutions
With this knowledge, you can manipulate solutions, either increasing their acidity or turning them into bases, to achieve desirable reactions or properties.
Logarithmic scale in chemistry
The logarithmic scale plays a vital role in chemistry, especially when handling pH levels. Unlike a linear scale, a logarithmic scale increases by powers of ten. For pH, this means that each whole number shift represents a tenfold increase or decrease in hydrogen ion concentration ([H鈦篯).The reason this scale is so effective is that it simplifies dealing with the vast range of hydrogen ion concentrations found in different solutions.
In practical terms, instead of dealing with incredibly small numbers like \(0.0000001\) M, you have a manageable figure such as 7.
This ease of representation is important:
  • Makes complex calculations more straightforward
  • Allows clearer comparison of different solutions
  • Useful for graphical representation and analysis of chemical data
These properties of the logarithmic scale help chemists efficiently categorize and compare solutions with varying acidity and basicity.

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