Chapter 14: Problem 68
Concentrated nitric acid is \(16 \mathrm{M}\). What volume of \(\mathrm{HNO}_{3}\) is diluted with distilled water to prepare \(5.00 \mathrm{~L}\) of \(0.10 \mathrm{M} \mathrm{HNO}_{3} ?\)
Short Answer
Expert verified
31.25 milliliters of concentrated nitric acid is needed.
Step by step solution
01
Identify Given Values
We are provided with the following information: the concentration of concentrated nitric acid is \(16\, \mathrm{M}\), the volume of the diluted solution required is \(5.00\, \mathrm{L}\), and the concentration of the diluted solution is \(0.10\, \mathrm{M}\).
02
Use the Dilution Formula
The dilution formula is \(C_1 \times V_1 = C_2 \times V_2\), where \(C_1\) is the initial concentration, \(V_1\) is the initial volume, \(C_2\) is the final concentration, and \(V_2\) is the final volume. Here, \(C_1 = 16\, \mathrm{M}\), \(C_2 = 0.10\, \mathrm{M}\), and \(V_2 = 5.00\, \mathrm{L}\). We need to find \(V_1\).
03
Rearrange the Dilution Formula
Rearrange the dilution formula to solve for \(V_1\): \( V_1 = \frac{C_2 \times V_2}{C_1} \).
04
Substitute Values and Calculate
Substitute the known values into the formula: \( V_1 = \frac{0.10\, \mathrm{M} \times 5.00\, \mathrm{L}}{16\, \mathrm{M}} \). Calculating this gives \( V_1 = \frac{0.50}{16} \).
05
Calculate Volume of Concentrated Acid
Perform the final calculation: \( V_1 = 0.03125 \) liters. Convert to milliliters if needed: \(0.03125 \times 1000 = 31.25\, \mathrm{mL}\).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molarity
Molarity is a measure of the concentration of a solution. It is calculated as the number of moles of solute (the substance being dissolved) per liter of solution. Molarity is expressed in mol/L and often denoted by the symbol "M." Here's how you can understand it in simple steps:
- Number of Moles: This refers to the amount of solute present in a solution. It's calculated using the formula:
\[ ext{Number of Moles} = rac{ ext{Mass of Solute (g)}}{ ext{Molar Mass (g/mol)}} \] - Volume of Solution: This is the total volume in which the solute is dissolved, measured in liters.
- Molarity Formula: Molarity can be calculated using the following formula:
\[ ext{Molarity (M)} = rac{ ext{Number of Moles}}{ ext{Volume (L)}} \]
Volume Calculation
Calculating volumes accurately is crucial when working with solutions. Volume calculation involves determining the amount of liquid necessary for a particular application, often in the context of dilution.
In the context of dilution:
- Initial Volume: This is the volume of the more concentrated solution you start with.
- Final Volume: This is the volume of the final diluted solution.
Dilution Formula
The dilution formula is a mathematical relationship that helps us calculate how to dilute a solution to a desired concentration. The basic form of this equation is:\[ C_1 \times V_1 = C_2 \times V_2 \]where:
- \(C_1\): Initial concentration of the solution (before dilution).
- \(V_1\): Volume of the initial (concentrated) solution required.
- \(C_2\): Final concentration of the solution (after dilution).
- \(V_2\): Volume of the final solution.