Chapter 13: Problem 18
Write out the electron configuration for each of the following nonmetal ions: (a) \(\mathrm{Br}^{-}\) (b) \(\mathrm{O}^{2-}\) (c) \(\mathrm{Se}^{2-}\) (d) \(\mathrm{N}^{3-}\)
Short Answer
Expert verified
(a) [Ar] 3d鈦 4s虏 4p鈦, (b) 1s虏 2s虏 2p鈦, (c) [Ar] 3d鹿鈦 4s虏 4p鈦, (d) 1s虏 2s虏 2p鈦.
Step by step solution
01
Understanding Electron Configuration
Electron configuration is a way to represent the distribution of electrons in an atom's electron shells and subshells. Electrons fill orbitals starting from the lowest energy level to the highest (Aufbau principle). To write the electron configuration of an ion, we first write the configuration for the neutral atom and then add or remove electrons depending on the charge of the ion.
02
Br鈦 Ion
The neutral bromine (Br) atom has an atomic number of 35, which means it has 35 electrons. Its electron configuration is: \[ \mathrm{Br}: [\mathrm{Ar}] \, 3d^{10} \, 4s^2 \, 4p^5 \].As Br鈦, it gains 1 electron to become \[ \mathrm{Br}^{-}: [\mathrm{Ar}] \, 3d^{10} \, 4s^2 \, 4p^6 \],which has the same configuration as Krypton (noble gas configuration).
03
O虏鈦 Ion
Oxygen (O) has an atomic number of 8, meaning it has 8 electrons. The neutral atom's configuration is: \[ \mathrm{O}: 1s^2 \, 2s^2 \, 2p^4 \].For O虏鈦, it gains 2 electrons becoming \[ \mathrm{O}^{2-}: 1s^2 \, 2s^2 \, 2p^6 \],which is the same as the electron configuration of Neon (noble gas configuration).
04
Se虏鈦 Ion
Selenium (Se) has an atomic number of 34. The neutral atom has an electron configuration of: \[ \mathrm{Se}: [\mathrm{Ar}] \, 3d^{10} \, 4s^2 \, 4p^4 \].When it gains two electrons to become Se虏鈦, the configuration becomes \[ \mathrm{Se}^{2-}: [\mathrm{Ar}] \, 3d^{10} \, 4s^2 \, 4p^6 \].Again, this resembles the configuration of Krypton.
05
N鲁鈦 Ion
Nitrogen (N) has an atomic number of 7, so its neutral atom configuration is: \[ \mathrm{N}: 1s^2 \, 2s^2 \, 2p^3 \].The N鲁鈦 ion gains 3 electrons, resulting in the configuration \[ \mathrm{N}^{3-}: 1s^2 \, 2s^2 \, 2p^6 \], which matches the electron configuration of Neon.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91影视!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Nonmetal Ions
Nonmetals are elements that tend to gain electrons during chemical reactions, forming negative ions, known as anions. These negatively charged ions are important in forming ionic compounds. In chemistry, ions like Br鈦, O虏鈦, Se虏鈦, and N鲁鈦 are examples of nonmetal ions.
When a nonmetal atom gains electrons, the added electrons join the existing electron configuration, filling up available electron shells to settle at lower energy levels.
For instance, when a bromine atom gains an electron, it results in a Br鈦 ion. This ion has an extra electron compared to the neutral atom, leading to a filled outer shell typical of a noble gas.
Nonmetal ions often achieve this stable electron arrangement 鈥 similar to that of noble gases 鈥 by gaining enough electrons to fill their outermost shells.
When a nonmetal atom gains electrons, the added electrons join the existing electron configuration, filling up available electron shells to settle at lower energy levels.
For instance, when a bromine atom gains an electron, it results in a Br鈦 ion. This ion has an extra electron compared to the neutral atom, leading to a filled outer shell typical of a noble gas.
Nonmetal ions often achieve this stable electron arrangement 鈥 similar to that of noble gases 鈥 by gaining enough electrons to fill their outermost shells.
Aufbau Principle
The Aufbau principle is a key concept in understanding how electron configurations are determined. It states that electrons are added one by one to atomic orbitals, starting from the lowest to higher energy levels. This principle helps explain the pattern of filling electron shells and subshells.
According to the Aufbau principle, electrons fill orbitals in a specific order:
According to the Aufbau principle, electrons fill orbitals in a specific order:
- The "s" subshells fill before the "p," "d," and "f" subshells within each shell, according to increasing energy.
- The sequence generally follows the order seen on the periodic table, which acts as a good guide for predicting electron configurations.
Noble Gas Configuration
Noble gas configuration refers to the fully filled set of electron shells found in noble gases, the group 18 elements in the periodic table.
Noble gases like Helium, Neon, and Krypton have particularly stable electron configurations, as they possess a full valence shell. This is why nonmetal ions adopt these configurations; achieving a noble gas configuration offers increased stability.
For example, when bromine gains one more electron to form Br鈦, it adopts the electron configuration of Krypton, which is \[ ext{[Ar]} \, 3d^{10} \, 4s^2 \, 4p^6 \].
L Similarly, O虏鈦 and N鲁鈦 adopt the electron configuration of Neon, \[ 1s^2 \, 2s^2 \, 2p^6 \]. Nonmetal ions striving for noble gas configuration showcase the drive towards stability in atomic structures.
Noble gases like Helium, Neon, and Krypton have particularly stable electron configurations, as they possess a full valence shell. This is why nonmetal ions adopt these configurations; achieving a noble gas configuration offers increased stability.
For example, when bromine gains one more electron to form Br鈦, it adopts the electron configuration of Krypton, which is \[ ext{[Ar]} \, 3d^{10} \, 4s^2 \, 4p^6 \].
L Similarly, O虏鈦 and N鲁鈦 adopt the electron configuration of Neon, \[ 1s^2 \, 2s^2 \, 2p^6 \]. Nonmetal ions striving for noble gas configuration showcase the drive towards stability in atomic structures.
Electron Shells and Subshells
Electron shells and subshells are the essential units used to understand how electrons are arranged in an atom.
An electron shell is at a specific distance from the nucleus and contains one or more electron subshells. These subshells are labeled s, p, d, and f, representing different shapes and energy levels.
An electron shell is at a specific distance from the nucleus and contains one or more electron subshells. These subshells are labeled s, p, d, and f, representing different shapes and energy levels.
- The s subshell can hold up to 2 electrons.
- The p subshell can hold up to 6 electrons.
- The d subshell is capable of holding 10 electrons.
- The f subshell can accommodate up to 14 electrons.