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Problem 80

What is the difference between intermolecular forces and intramolecular forces? Which are stronger?

Problem 83

Draw the three-dimensional shape of methanol, \(\mathrm{CH}_{3} \mathrm{OH}\). Indicate the numeric value of all bond angles. Is this molecule polar? If so, draw the molecular dipole moment vector.

Problem 85

Explain the difference between electron-group geometry and molecular shape. How do you use electron-group geometry when deciding what shape a molecule has?

Problem 90

Which should have the largest dipole moment: \(\mathrm{O}_{3}, \mathrm{H}_{2} \mathrm{O}\), or \(\mathrm{OF}_{2} ?\)

Problem 93

Draw each ion or molecule showing its threedimensional shape and valence electrons. For each species, name the electron-group geometry around the central atom (or atoms) and the molecular shape. Indicate whether each species has a molecular dipole moment. If so, draw the dipole moment vector. (a) \(\mathrm{NCCN}\) (b) \(\mathrm{BF}_{4}\) (c) \(\mathrm{NClO}_{2}\) (d) \(\mathrm{SeH}_{2}\)

Problem 94

White phosphorus, \(\mathrm{P}_{4}\), consists of four phosphorus atoms, with each atom bonded to the other three. Draw the three-dimensional shape of this molecule, showing all valence electrons and bond angles. (Hint: Begin by drawing one atom bonded to the three others using VSEPR theory, and then make the remaining connections.)

Problem 100

Some molecules have central atoms with steric numbers greater than 4 . For example, the central sulfur atom in \(\mathrm{SF}_{6}\) has a steric number of 6 . Its actual geometry (called octahedral), is shown below (all the bond angles are \(90^{\circ}\) or \(180^{\circ}\) ). (a) Are the bonds in \(\mathrm{SF}_{6}\) polar, polar covalent, or ionic? Explain. (b) Would you predict the \(\mathrm{SF}_{6}\) molecule to be polar or nonpolar? Justify your answer.

Problem 110

One student claims \(\mathrm{XeF}_{4}\) will be polar. Another claims it will be nonpolar. Which is right, and why?

Problem 111

Is CIFs polar or nonpolar? Fully explain your answer.

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