Chapter 15: Problem 43
List the three criteria early chemists used to classify a compound as a base.
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Chapter 15: Problem 43
List the three criteria early chemists used to classify a compound as a base.
These are the key concepts you need to understand to accurately answer the question.
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Amines are organic compounds that contain an \(\mathrm{NH}_{2}\) group, and water-soluble amines are weak bases in water. For example, the compound methylamine, \(\mathrm{H}_{3} \mathrm{C}-\mathrm{NH}_{2}\), is a weak base. (a) Draw a dot diagram for methylamine. (b) Using dot diagrams, show the equilibrium reaction between methylamine and water. (c) To which side does the equilibrium in part (b) lie? What did we tell you that allowed you to figure out the answer? (d) The similar compound ethane, \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{3}\), does not act as a weak base. Why can methylamine act as a weak base but \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{3}\) can't? (Hint: Draw a dot diagram for \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{3}\).) (e) Is it appropriate to call methylamine an electrolyte? If so, is it weak or strong? Explain.
Can a buffer resist \(\mathrm{pH}\) changes for any added amount of strong acid or base? Explain.
Ethanol, \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\), and hydride ion, \(\mathrm{H}^{-}\), react to produce \(\mathrm{H}_{2}\) gas and the \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}\) anion. Arrhenius could not tell you what is going on, but Bronsted and Lowry would have no trouble. How would they explain this reaction?
Is it possible to obtain water at \(25{ }^{\circ} \mathrm{C}\) that contains absolutely no ions of any sort? Explain.
Citric acid, \(\mathrm{H}_{3} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}\), is a weak triprotic acid. Write equations for the three equilibrium reactions that occur during the stepwise dissociation of citric acid in water.
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