Chapter 15: Problem 203
Rewrite this acid-base reaction in dot-diagram form, and then use an arrow to show the proton being transferred and label the Br酶nsted-Lowry acid and base: \(\mathrm{F}^{-}+\mathrm{NH}_{4}^{+} \rightleftarrows \mathrm{HF}+\mathrm{NH}_{3}\)
Short Answer
Expert verified
In dot-diagram form, the acid-base reaction is shown as:
F鈦(base) + NH鈧勨伜(acid) 鈬 HF + NH鈧
with an arrow from the lone electron pair of F鈦 to a hydrogen atom in NH鈧勨伜, and another arrow from the N-H bond back to the nitrogen atom in NH鈧勨伜, representing the proton transfer. The Br酶nsted-Lowry acid is NH鈧勨伜, and the Br酶nsted-Lowry base is F鈦.
Step by step solution
01
Draw Lewis Dot Structures for Chemical Species
Draw the Lewis dot structures for F鈦, NH鈧勨伜, HF, and NH鈧 as follows:
- F鈦: Seven valence electrons for fluorine, plus one extra electron from its negative charge, resulting in eight electrons in total. Arrange them in pairs around the fluorine atom.
- NH鈧勨伜: Nitrogen has five valence electrons, and there are four hydrogens, each contributing one electron. So, there are nine electrons in total for this molecule. However, due to the positive charge, one electron is removed, leaving eight electrons in total. Arrange them in pairs around the nitrogen atom, and connect them to the hydrogen atoms.
- HF: Fluorine has seven valence electrons, and hydrogen has one valence electron. Arrange them around the respective atoms and connect them with a single bond.
- NH鈧: Nitrogen has five valence electrons, and there are three hydrogens, each contributing one electron. Arrange the eight electrons in pairs around the nitrogen atom and connect them to the hydrogen atoms.
02
Show Proton Transfer with Arrows
Now, let's show the proton transfer between the F鈦 ion and the NH鈧勨伜 ion using arrows.
1. Draw an arrow from the lone electron pair of F鈦 to one of the hydrogen atoms connected to the nitrogen atom in NH鈧勨伜. This arrow represents the electron pair accepting a proton from NH鈧勨伜.
2. Draw another arrow from the N-H bond (where the proton is being transferred) to the nitrogen atom in NH鈧勨伜. This arrow represents the donation of the electron pair back to the nitrogen after the proton transfer.
03
Label Br酶nsted-Lowry Acid and Base
Finally, we identify and label the Br酶nsted-Lowry acid and base in the reaction, remembering that an acid donates a proton and a base accepts a proton.
1. NH鈧勨伜 donates a proton (H鈦) to F鈦, so it is the Br酶nsted-Lowry acid.
2. F鈦 accepts the proton from NH鈧勨伜, so it is the Br酶nsted-Lowry base.
In summary, the reaction is shown with the Lewis dot structures, the proton transfer arrows, and the identification of the Br酶nsted-Lowry acid and the base as follows:
F鈦(base) + NH鈧勨伜(acid) 鈬 HF + NH鈧
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Lewis Dot Structures
Lewis dot structures are visual representations of the valence electrons in a molecule or ion. These diagrams help us understand the bonding and non-bonding electrons within a chemical species and play a crucial role in predicting the behavior of atoms in chemical reactions. In the given exercise, drawing Lewis dot structures for F鈦, NH鈧勨伜, HF, and NH鈧 provides insight into their electronic configuration. For example, the extra electron on the fluorine anion, F鈦, is depicted as a pair, indicating its full octet and readiness to engage in chemical bonding, particularly in acid-base reactions.
When using Lewis dot structures to illustrate reactions, it's essential to follow the 'octet rule,' which suggests that atoms are generally more stable when they have eight electrons in their outermost shell, mimicking the electron configuration of noble gases. The exception is hydrogen, which follows the 'duet rule' and is most stable with two electrons.
When using Lewis dot structures to illustrate reactions, it's essential to follow the 'octet rule,' which suggests that atoms are generally more stable when they have eight electrons in their outermost shell, mimicking the electron configuration of noble gases. The exception is hydrogen, which follows the 'duet rule' and is most stable with two electrons.
Proton Transfer
Proton transfer is a fundamental concept in acid-base chemistry. It is the process by which a hydrogen ion (H鈦), which is simply a proton, is transferred from one chemical species to another. In the exercise, NH鈧勨伜 (the Br酶nsted-Lowry acid) transfers a proton to the F鈦 ion (the Br酶nsted-Lowry base), converting it to HF and NH鈧. The ability to depict this movement with arrows in a Lewis dot structure not only aids in visualizing the reaction mechanism but also reinforces understanding of how acids and bases interact according to the Br酶nsted-Lowry theory.
The direction of the arrow is significant; it goes from the electron donor (the base) to the electron acceptor (the acid). This helps students understand the flow of electrons during the formation and breaking of chemical bonds and the key role of proton transfer in acid-base reactions.
The direction of the arrow is significant; it goes from the electron donor (the base) to the electron acceptor (the acid). This helps students understand the flow of electrons during the formation and breaking of chemical bonds and the key role of proton transfer in acid-base reactions.
Acid-Base Reaction
An acid-base reaction is a chemical reaction that involves the transfer of a proton from an acid to a base. In the context of the Br酶nsted-Lowry acid-base theory, an acid is defined as a proton donor, and a base as a proton acceptor. This theory expands the definition of acids and bases beyond the substances that can donate H鈦 in water, allowing a larger variety of compounds to be classified as acids or bases.
In the given exercise, the reaction between F鈦 and NH鈧勨伜 is a classic example of an acid-base reaction, where the proton is transferred from the acid (NH鈧勨伜) to the base (F鈦). Acid-base reactions are ubiquitous in chemistry and are responsible for a range of phenomena, from the bubbles in carbonated beverages to the digestion of food in our stomachs. Understanding these reactions is critical for grasping more complex chemical processes.
In the given exercise, the reaction between F鈦 and NH鈧勨伜 is a classic example of an acid-base reaction, where the proton is transferred from the acid (NH鈧勨伜) to the base (F鈦). Acid-base reactions are ubiquitous in chemistry and are responsible for a range of phenomena, from the bubbles in carbonated beverages to the digestion of food in our stomachs. Understanding these reactions is critical for grasping more complex chemical processes.
Chemical Species
Chemical species are the specific forms that matter can take: atoms, molecules, ions, radicals, etc. In a given chemical reaction, each chemical species plays a distinct role based on its molecular structure and properties. By examining Lewis dot structures, we can better categorize each species as an acid or a base, as the exercise demonstrates.
Identifying species involved in an acid-base reaction is crucial for understanding the nature of the reaction and predicting the products. For instance, the positive charge of the NH鈧勨伜 ion makes it a likely candidate for a Br酶nsted-Lowry acid, as it has a disposition to donate a proton. Conversely, the presence of a lone pair of electrons on F鈦 indicates its potential to act as a Br酶nsted-Lowry base by accepting a proton.
Identifying species involved in an acid-base reaction is crucial for understanding the nature of the reaction and predicting the products. For instance, the positive charge of the NH鈧勨伜 ion makes it a likely candidate for a Br酶nsted-Lowry acid, as it has a disposition to donate a proton. Conversely, the presence of a lone pair of electrons on F鈦 indicates its potential to act as a Br酶nsted-Lowry base by accepting a proton.
Valence Electrons
Valence electrons are the outermost electrons of an atom and are critical in determining the chemical properties and reactivity of the element. It is these electrons that participate in chemical bonding and reactions. In the given exercise, understanding the number and arrangement of valence electrons through Lewis dot structures is key to predicting how NH鈧勨伜 will donate a proton to F鈦.
The valence electrons influence the formation of chemical bonds, whether by sharing electrons, as in covalent bonds, or by actual electron transfer, as in the formation of ions. They are fundamental to all chemical reactions and dictate how a particle behaves under different chemical conditions. Comprehending their role provides a foundation for understanding more complex chemical bonding and interactions.
The valence electrons influence the formation of chemical bonds, whether by sharing electrons, as in covalent bonds, or by actual electron transfer, as in the formation of ions. They are fundamental to all chemical reactions and dictate how a particle behaves under different chemical conditions. Comprehending their role provides a foundation for understanding more complex chemical bonding and interactions.