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The pH of a solution is \(-1\). What are the \(\mathrm{H}_{3} \mathrm{O}^{+}\) and OH concentrations? Is the solution acidic or basic?

Short Answer

Expert verified
Given the pH of -1, the concentration of H鈧僌鈦 ions can be calculated as \( [H_{3}O^+] = 10^{-(-1)} = 10 \) moles/L. Using the ion product of water, the concentration of OH鈦 ions is found to be \( [OH^-] = \frac{1 \times 10^{-14}}{10} = 1 \times 10^{-15} \) moles/L. Since the H鈧僌鈦 concentration is greater than the OH鈦 concentration, the solution is acidic.

Step by step solution

01

Recall the definition of pH

The pH of a solution is defined as the negative logarithm of the H鈧僌鈦 concentration: \( pH = -\log{[H_{3}O^+]} \) where [H鈧僌鈦篯 represents the concentration of hydronium ions in the solution,
02

Calculate the H鈧僌鈦 concentration

Given the pH value of -1, we can rearrange the formula to find the H鈧僌鈦 concentration: \[ [H_{3}O^+] = 10^{-pH} \] Substitute pH value and compute the concentration: \[ [H_{3}O^+] = 10^{-(-1)} = 10 \] So, the concentration of H鈧僌鈦 in the solution is 10 moles/L.
03

Recall the relationship between H鈧僌鈦 and OH鈦 concentrations

The relationship between H鈧僌鈦 and OH鈦 concentrations can be described using the ion product of water (Kw): \[ K_w = [H_{3}O^+][OH^-] \] For pure water at 25掳C, Kw value is 1 x 10鈦宦光伌.
04

Calculate the OH鈦 concentration

Using the Kw value and the calculated H鈧僌鈦 concentration, find the concentration of OH鈦 ions: \[ [OH^-] = \frac{K_w}{[H_{3}O^+]} \] Substitute the values and compute the concentration: \[ [OH^-] = \frac{1 \times 10^{-14}}{10} = 1 \times 10^{-15} \] So, the concentration of OH鈦 ions in the solution is 1 x 10鈦宦光伒 moles/L.
05

Determine if the solution is acidic or basic

A solution is considered acidic if the H鈧僌鈦 concentration is greater than the OH鈦 concentration, and it's considered basic if the OH鈦 concentration is greater than the H鈧僌鈦 concentration. Since the H鈧僌鈦 concentration (10 moles/L) is greater than the OH鈦 concentration (1 x 10鈦宦光伒 moles/L), the solution is acidic.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydronium Ion Concentration
The hydronium ion concentration, often represented as \[H_{3}O^+\], is a key factor in determining the acidity of a solution. It reflects the amount of hydronium ions present, which are formed when water molecules gain a hydrogen ion \((H^+)\). \[H_{3}O^+\] is connected to the pH scale, which measures how acidic or basic a solution is.

The pH is calculated using the formula:


\( pH = -\log{[H_{3}O^+]} \)


When you have a pH value, you can easily determine the \[H_{3}O^+\] concentration by rearranging the equation:


\[ [H_{3}O^+] = 10^{-pH} \]


  • If a solution has a high \[H_{3}O^+\] concentration, it means the solution is more acidic.
  • Given a pH of -1, the \[H_{3}O^+\] concentration in our example turns out to be 10 moles/L, reflecting very high acidity.
OH Minus Concentration
The concentration of hydroxide ions in a solution is denoted as \[OH^-\]. This component is crucial in determining the basicity of the solution. Hydroxide ions are essentially part of the balance between acids and bases in water.

To find the \[OH^-\] concentration, we use the relationship between \[H_{3}O^+\] and \[OH^-\] concentrations which is governed by the ion product of water (\(K_w\)):


\[ K_w = [H_{3}O^+][OH^-] \]


For pure water at 25掳C, \(K_w\) is constant, equal to \(1 \times 10^{-14}\). This means we can explore how acid and base concentrations are inversely related:


\[ [OH^-] = \frac{K_w}{[H_{3}O^+]} \]


  • Substituting values allows calculation: \([OH^-] = \frac{1 \times 10^{-14}}{10}\), resulting in \([OH^-] = 1 \times 10^{-15} \) moles/L.
  • A low \[OH^-\] concentration alongside a high \[H_{3}O^+\] concentration reinforces the acidity of the solution.
Acidic or Basic Solution
To determine whether a solution is acidic or basic, compare the concentrations of hydronium ions (\(H_{3}O^+\)) and hydroxide ions (\(OH^-\)). The nature of the solution is judged by this comparison:
  • If \[H_{3}O^+\] concentration is greater than \[OH^-\], the solution is acidic.
  • If \[OH^-\] concentration exceeds \[H_{3}O^+\], the solution is basic.

From the provided example, where \[H_{3}O^+\] concentration is 10 moles/L and \[OH^-\] concentration is \(1 \times 10^{-15}\) moles/L, it's evident that:


  • The solution has significantly more hydronium ions than hydroxide ions.
  • This results in an acidic solution, confirming the direct impact of these ion concentrations on the nature of the solution.

Thus, understanding these ion concentrations helps classify a solution and predict its behavior in chemical reactions.

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