/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 67 Which has the greater hydration ... [FREE SOLUTION] | 91影视

91影视

Which has the greater hydration energy, \(\mathrm{AlCl}_{3}\) or NaCl? Explain your answer.

Short Answer

Expert verified
AlCl鈧 has a greater hydration energy than NaCl, as the Al鲁鈦 ion is smaller and more highly charged than the Na鈦 ion, leading to stronger electrostatic interactions between the ion and water molecules. This results in a larger amount of energy being released during the hydration process.

Step by step solution

01

Define hydration energy

Hydration energy is the energy that is released when one mole of gaseous ions combines with water to form hydrated ions. It is an exothermic process and its value depends on the size and charge of the ions being hydrated. Smaller and more highly charged ions typically have higher hydration energies.
02

Identify the ions in AlCl鈧 and NaCl

In AlCl鈧, we have the aluminum ion, Al鲁鈦, and the chloride ion, Cl鈦. In NaCl, we have the sodium ion, Na鈦, and the chloride ion, Cl鈦.
03

Compare the size and charge of Al鲁鈦 and Na鈦 ions

The aluminum ion, Al鲁鈦, is smaller and has a higher charge (3鈦) than the sodium ion, Na鈦 (1鈦). This means that Al鲁鈦 ions will exhibit stronger electrostatic interactions with water's polar molecules due to their higher charge, leading to a larger hydration energy.
04

Compare the hydration energies of AlCl鈧 and NaCl

Since the hydration energy is determined mainly by the cations (Al鲁鈦 and Na鈦) in the salts, we can compare their hydration energies based on these cations' properties. As mentioned earlier, Al鲁鈦 has a higher charge and is smaller than Na鈦. This indicates that AlCl鈧 will have a higher hydration energy compared to NaCl.
05

Conclusion

AlCl鈧 has a greater hydration energy than NaCl, as the Al鲁鈦 ion is smaller and more highly charged than the Na鈦 ion, leading to stronger electrostatic interactions between the ion and water molecules. This results in a larger amount of energy being released during the hydration process.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ionic Compounds
Ionic compounds are fascinating structures formed when metals combine with non-metals to create a lattice of charged particles, known as ions. These compounds result from the complete transfer of electrons between atoms.
For example, in the formation of sodium chloride (NaCl), a sodium atom donates an electron to a chlorine atom. This forms sodium ions, Na鈦, and chloride ions, Cl鈦.
Some key features define ionic compounds:
  • They are generally solid at room temperature.
  • They have high melting and boiling points.
  • They dissolve easily in water, thanks to the interaction between the ions and the polar water molecules.
  • Their crystal structures are arranged in a repeating pattern that maximizes attractive forces and minimizes repulsive forces.
Understanding ionic compounds is essential for grasping how different substances interact with their environment, especially in a solution setting like water.
Charge and Size of Ions
The charge and size of ions are crucial factors in determining their chemical behavior, particularly in solutions. The charge of an ion is essentially its oxidation state, indicated by the number of electrons lost or gained from its parent atom.
Ions with a higher charge, like Al鲁鈦 or Fe鲁鈦, have stronger interactions with opposite charges, than those with a lower charge, like Na鈦 or K鈦. The highly charged ions are more prone to lead complex chemical behaviors, such as higher hydration energies.
Additionally, the size of ions plays a significant role in determining their interaction strength. Smaller ions, like Li鈦 compared to K鈦, can pack more tightly and bond more strongly with other ions and molecules in their surroundings.
  • Small ions with high charges typically have greater attraction to opposite charges, leading to higher hydration energies.
  • These factors altogether influence properties such as the solubility and stability of ionic compounds.
Electrostatic Interactions
Electrostatic interactions are the forces that occur between charged particles or ions. These interactions are pivotal in the understanding of molecular and ionic behaviors, especially in aqueous environments.
In aqueous solutions, water molecules interact with ions predominantly through electrostatic forces. Water, being polar, has a partial negative charge on the oxygen and partial positive charges on the hydrogens.
  • The attraction between the water molecules and anions, like Cl鈦, occurs at the hydrogen ends of the water molecules.
  • Meanwhile, cations, like Na鈦, attract the oxygen end, leading to hydration.
This is why smaller ions or ions with higher charges, such as Al鲁鈦, enhance electrostatic interactions, resulting in greater hydration energies. Electrostatic interactions are critical in many biological and chemical processes, defining how substances dissolve and react in water.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Study anywhere. Anytime. Across all devices.