Chapter 10: Problem 25
How is electricity similar to water flowing in hose?
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Chapter 10: Problem 25
How is electricity similar to water flowing in hose?
These are the key concepts you need to understand to accurately answer the question.
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Assign an oxidation number to each atom and identify the oxidizing agent and reducing agent: \(3 \mathrm{Na}_{2} \mathrm{SO}_{3}+2 \mathrm{KMnO}_{4}+\mathrm{H}_{2} \mathrm{O} \rightarrow\) \(3 \mathrm{Na}_{2} \mathrm{SO}_{4}+2 \mathrm{MnO}_{2}+2 \mathrm{KOH}\)
What do the terms oxidation and reduction mean with regard to valence electrons?
Lithium is a very active metal, so active that it reacts with water to make flammable hydrogen gas. \(\mathrm{Li}(s)+\mathrm{H}_{2} \mathrm{O}(l) \rightarrow \mathrm{LiOH}(s)+1 / 2 \mathrm{H}_{2}(g)\) (a) What metal would you use in combination with Li to make a battery having the highest voltage? (Consult the EMF series.) (b) Too rapid a discharge of a lithium battery (which can occur if there is a short circuit) can overheat a lithium battery and cause it to explode and catch fire. Why is trying to put out such a fire with water a bad idea? (c) Would lithium be the anode or cathode in a lithium ion battery? Explain.
Consider the perchlorate \(\left(\mathrm{ClO}_{4}^{-}\right)\) ion. (a) Assign oxidation states to all of the atoms in perchlorate. (b) Explain why the chlorine atom in perchlorate does not follow the halide rule. (c) Do you think perchlorate would be a powerful oxidizing agent or a powerful reducing agent? Explain. (d) Would it be possible to have an even higher oxidation state for the \(C 1\) atom in some other compound? Explain. (Hint: Chlorine is in group VIIA).
Which of the following are electron-transfer reactions? For those that are, indicate which reactant is the reducing agent and which reactant is the oxidizing agent. (a) \(\mathrm{PF}_{3}+3 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{3} \mathrm{PO}_{3}+3 \mathrm{HF}\) (b) \(\mathrm{H}_{2}+\mathrm{Cl}_{2} \rightarrow 2 \mathrm{HCl}\) (c) \(2 \mathrm{Cr}_{2} \mathrm{O}_{3}+3 \mathrm{Si} \rightarrow 4 \mathrm{Cr}+3 \mathrm{SiO}_{2}\) (d) \(\mathrm{HCl}+\mathrm{NaOH} \rightarrow \mathrm{NaCl}+\mathrm{H}_{2} \mathrm{O}\)
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