Chapter 10: Problem 17
\(\mathrm{Ca}+2 \mathrm{H}^{+} \rightarrow \mathrm{Ca}^{2+}+\mathrm{H}_{2}\)
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Chapter 10: Problem 17
\(\mathrm{Ca}+2 \mathrm{H}^{+} \rightarrow \mathrm{Ca}^{2+}+\mathrm{H}_{2}\)
These are the key concepts you need to understand to accurately answer the question.
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The following reaction is responsible for producing electricity in your car battery (often called a lead storage battery): \(\mathrm{Pb}+\mathrm{PbO}_{2}+2 \mathrm{H}_{2} \mathrm{SO}_{4} \rightarrow 2 \mathrm{PbSO}_{4}+2 \mathrm{H}_{2} \mathrm{O}\) (a) Assign an oxidation state to each atom. (Hint: For \(\mathrm{PbSO}_{4}\), you can figure out the charge of the \(\mathrm{Pb}\) if you remember that the charge of the sulfate ion is \(-2\left(\mathrm{SO}_{4}^{2-}\right)\). Then use shortcut Rule 7 to get the oxidation state of the \(\mathrm{Pb}\) in \(\mathrm{PbSO}_{4}\).) (b) Identify the atom that gets oxidized and the atom that gets reduced. (c) Identify the reactant that is the oxidizing agent and the reactant that is the reducing agent.
Assign an oxidation state to each carbon in: (a) \(\mathrm{H}_{3} \mathrm{CCH}_{3}\) (b) \(\mathrm{H}_{2} \mathrm{CCH}_{2}\) (c) HCCH
Which of the following are electron-transfer reactions? For those that are, indicate which reactant is the reducing agent and which reactant is the oxidizing agent. (a) \(3 \mathrm{H}_{2} \mathrm{SO}_{3}+2 \mathrm{HNO}_{3} \rightarrow 3 \mathrm{H}_{2} \mathrm{SO}_{4}+2 \mathrm{NO}+\mathrm{H}_{2} \mathrm{O}\) (b) \(\mathrm{Mg}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{Mg}(\mathrm{OH})_{2}+\mathrm{H}_{2}\) (c) \(\mathrm{SO}_{3}{ }^{2-}+2 \mathrm{H}^{+} \rightarrow \mathrm{SO}_{2}+\mathrm{H}_{2} \mathrm{O}\) (d) \(\mathrm{PbO}+\mathrm{CO} \rightarrow \mathrm{Pb}+\mathrm{CO}_{2}\)
A student claims that in his battery, the electrons flow from the positive to the negative electrode. In fact, this is not true for any battery. Explain why electrons would never flow in this direction and how the direction of electron flow tells you that the cathode is where reduction occurs.
Draw a Lewis dot diagram for \(\mathrm{H}_{2} \mathrm{O}_{2}\) (hydrogen peroxide), and use the oxidation-state method of electron bookkeeping to determine how many electrons each atom should be assigned.
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