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Barium chloride solutions are used in chemical analysis for the quantitative precipitation of sulfate ion from solution. $$ \mathrm{Ba}^{2+}(a q)+\mathrm{SO}_{4}^{2-}(a q) \rightarrow \mathrm{BaSO}_{4}(s) $$ Suppose a solution is known to contain on the order of \(150 \mathrm{mg}\) of sulfate ion. What mass of barium chloride should be added to guarantee precipitation of all the sulfate ion?

Short Answer

Expert verified
The mass of barium chloride (\(\mathrm{BaCl}_{2}\)) required to precipitate all the sulfate ion (\(\mathrm{SO}_{4}^{2-}\)) present in the solution (150 mg) is 0.325 g.

Step by step solution

01

Write down the balanced chemical equation

In this case, the balanced chemical equation is already provided: \[ \mathrm{Ba}^{2+}(aq) + \mathrm{SO}_{4}^{2-}(aq) \rightarrow \mathrm{BaSO}_{4}(s) \]
02

Determine the number of moles of sulfate ions

Given that there are 150 mg of sulfate ions, we need to convert this mass into moles. First, find the molar mass of sulfate ion (SO鈧劼测伝): Molar mass of S = 32.06 g/mol Molar mass of O = 16.00 g/mol Molar mass of SO鈧劼测伝 = 32.06 + (4 脳 16.00) = 96.06 g/mol Now, convert the mass of sulfate (150 mg) to moles: Mass of sulfate = 150 mg = 0.150 g Number of moles of sulfate ions = mass / molar mass Number of moles of sulfate ions = \( \frac{0.150 \,\text{g}}{96.06\, \text{g/mol}} \) = 1.56 脳 10鈦宦 moles
03

Use the stoichiometry of the balanced equation to determine the moles of barium chloride needed

From the balanced equation, the mole ratio of \(\mathrm{Ba}^{2+}\) ion to \(\mathrm{SO}_{4}^{2-}\) ion is 1:1. Therefore, the moles of \(\mathrm{Ba}^{2+}\) ions required are equal to the moles of sulfate ions: Moles of \(\mathrm{Ba}^{2+}\) ions = 1.56 脳 10鈦宦 moles Since barium chloride (\(\mathrm{BaCl}_{2}\)) provides the \(\mathrm{Ba}^{2+}\) ions, the moles of \(\mathrm{BaCl}_{2}\) required will be equal to the moles of \(\mathrm{Ba}^{2+}\) ions needed. Moles of \(\mathrm{BaCl}_{2}\) = 1.56 脳 10鈦宦 moles
04

Convert moles of barium chloride to mass

Now, we need to find the mass of the barium chloride required. First, determine the molar mass of barium chloride (\(\mathrm{BaCl}_{2}\)): Molar mass of Ba = 137.33 g/mol Molar mass of Cl = 35.45 g/mol Molar mass of \(\mathrm{BaCl}_{2}\) = 137.33 + (2 脳 35.45) = 208.23 g/mol Next, use the number of moles of \(\mathrm{BaCl}_{2}\) to find its mass: Mass of \(\mathrm{BaCl}_{2}\) = moles 脳 molar mass Mass of \(\mathrm{BaCl}_{2}\) = (1.56 脳 10鈦宦 moles) 脳 (208.23 g/mol) = 0.325 g Thus, the mass of barium chloride required to precipitate all the sulfate ion present in the solution (150 mg) is 0.325 g.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reaction
A chemical reaction involves the transformation of one or more substances into new products. This process is depicted using chemical equations, which provide a symbolic representation of the reactants and the products. For example, in the reaction \( \mathrm{Ba}^{2+}(aq) + \mathrm{SO}_{4}^{2-}(aq) \rightarrow \mathrm{BaSO}_{4}(s) \), barium ions and sulfate ions react to form solid barium sulfate. This is a prime example of a precipitation reaction, where the formation of a solid from aqueous ions occurs.
  • Reactants: Substances that undergo change, in this case, \( \mathrm{Ba}^{2+} \) and \( \mathrm{SO}_{4}^{2-} \).
  • Products: New substances formed, in this scenario \( \mathrm{BaSO}_{4} \).
Chemical reactions are governed by the principle of conservation of mass, which means the total mass of the products equals that of the reactants. This concept is crucial in quantitative analysis, as it ensures accurate measurement and calculation of the components involved.
Moles Calculation
Calculating moles is a pivotal part of stoichiometry, which deals with quantitative relationships in chemical equations. To perform moles calculation, you need the mass of the substance and its molar mass (the mass of one mole of a substance).First, determine the molar mass. For sulfate \( \text{SO}_4^{2-} \), the molar mass is calculated based on its atomic components.
  • Sulfur (S): 32.06 g/mol
  • Oxygen (O): 16.00 g/mol
  • Molar mass of \( \text{SO}_4^{2-} \): 96.06 g/mol
Next, convert the provided mass to moles:\[\text{Moles} = \frac{\text{Given mass (g)}}{\text{Molar mass (g/mol)}}\]Given a sulfate mass of 0.150 grams, the number of moles is:\[\frac{0.150 \text{g}}{96.06 \text{g/mol}} = 1.56 \times 10^{-3} \text{ moles}\]This straightforward calculation is essential in determining the quantities required in a chemical reaction.
Precipitation Reaction
A precipitation reaction involves the formation of an insoluble solid from the reaction of two soluble substances in a solution. In our example, the reaction between \( \text{Ba}^{2+} \) ions and \( \text{SO}_4^{2-} \) ions produces barium sulfate (\( \text{BaSO}_4 \)), a solid precipitate.
  • Occurs when product is insoluble in water.
  • Common in qualitative analysis, helping determine presence of specific ions.
In our reaction:\( \text{Ba}^{2+}(aq) + \text{SO}_4^{2-}(aq) \rightarrow \text{BaSO}_4(s) \)The reaction stops when either of the reacting ions is completely used, which helps in controlling the purity and yield of the desired product. This reaction is a practical way of removing ions from solutions, showing the utility of stoichiometry in industrial and laboratory processes.
Quantitative Analysis
Quantitative analysis refers to the measurement of the amount or concentration of substances in a sample. In the context of our chemical reaction, it involves calculating the precise amount of barium chloride needed to completely precipitate sulfate ions from a solution.Start by using stoichiometry to understand the mole relationships between reactants and products. The balanced equation shows a 1:1 molar ratio:
  • \( \text{Moles of } \text{Ba}^{2+} = \text{Moles of } \text{SO}_4^{2-} \)
Apply this ratio to determine the exact amount of barium chloride required:
  • Given 1.56 \times 10^{-3} moles of sulfate, equivalent moles of \( \text{BaCl}_2 \) are needed.
Finally, convert moles to mass using the molar mass of \( \text{BaCl}_2 \) (208.23 g/mol):\[\text{Mass} = 1.56 \times 10^{-3} \text{ moles} \times 208.23 \text{ g/mol} = 0.325 \text{ g}\]This calculated mass of barium chloride ensures complete reaction with the sulfate ions, showcasing the precision of quantitative analysis.

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Most popular questions from this chapter

What do the coefficients of a balanced chemical equation tell us about the proportions in which atoms and molecules react on an individual (microscopic) basis?

For each of the following unbalanced chemical equations, suppose that exactly \(1.00 \mathrm{~g}\) of each reactant is taken. Determine which reactant is limiting, and calculate what mass of the product in boldface is expected (assuming that the limiting reactant is completely consumed). a. \(\mathrm{CS}_{2}(l)+\mathrm{O}_{2}(g) \rightarrow \mathrm{CO}_{2}(g)+\mathrm{SO}_{2}(g)\) b. \(\mathrm{NH}_{3}(g)+\mathrm{CO}_{2}(g) \rightarrow \mathrm{CN}_{2} \mathrm{H}_{4} \mathrm{O}(s)+\mathrm{H}_{2} \mathrm{O}(g)\) c. \(\mathrm{H}_{2}(g)+\mathrm{MnO}_{2}(s) \rightarrow \mathrm{MnO}(s)+\mathbf{H}_{2} \mathrm{O}(g)\) d. \(\mathrm{I}_{2}(l)+\mathrm{Cl}_{2}(g) \rightarrow \mathbf{I C l}(g)\)

When the sugar glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{0},\) is burned in air, carbon dioxide and water vapor are produced. Write the balanced chemical equation for this process, and calculate the theorctical yield of carbon dioxide when \(1.00 \mathrm{~g}\) of glucose is burned completely.

Explain how one determines which reactant in a process is the limiting reactant. Does this depend only on the masses of the reactant present? Give an example of how to determine the limiting reactant by using a Before-Change- After (BCA) table with a balanced chemical cquation and reactant starting amounts.

4Which of the following statements is true for the reaction of nitrogen gas with hydrogen gas to produce ammonia \(\left(\mathrm{NH}_{3}\right){ }^{7}\) Choose the best answer. a. Subscripts can be changed to balance this equation, just as they can be changed to balance the charges when writing the formula for an ionic compound. b. The nitrogen and hydrogen will not react until you have added the correct mole ratios. c. The mole ratio of nitrogen to hydrogen in the balanced equation is 1: 2 . A Ammonia will not form unless 1 mole of nitrogen and 3 moles of hydrogen have been added. c. The balanced cquation allows you to predict how much ammonia you will make based on the amount of nitrogen and hydrogen present.

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