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Which of the following do not represent a conjugate acid-base pair? For those pairs that are not conjugate acid-base pairs, write the correct conjugate acid-base pair for each species in the pair. a. HI \(, \mathrm{I}^{-}\) b. \(\mathrm{HClO}, \mathrm{HClO}_{2}\) c. \(\mathrm{H}_{3} \mathrm{PO}_{4}, \mathrm{PO}_{4}^{3-}\) d. \(\mathrm{H}_{2} \mathrm{CO}_{3}, \mathrm{CO}_{3}^{2-}\)

Short Answer

Expert verified
The pairs a, c, and d are not conjugate acid-base pairs. The correct conjugate acid-base pairs for each species are: a. (HI, I鈦) - Conjugate acid-base pair b. (HClO, ClO鈦) and (HClO鈧, ClO鈧傗伝) c. (H鈧働O鈧, H鈧侾O鈧勨伝) and (HPO鈧劼测伝, PO鈧劼斥伝) d. (H鈧侰O鈧, HCO鈧冣伝) and (HCO鈧冣伝, CO鈧兟测伝)

Step by step solution

01

Analyzing the pair

HI is an acid that can donate a proton H鈦 to I鈦 to form I虏鈦. I鈦 is thus the conjugate base of the acid HI. Therefore, HI and I鈦 represent a conjugate acid-base pair. b. HClO, HClO鈧
02

Analyzing the pair

In this case, HClO鈧 has one more proton (H鈦) compared to HClO. However, these two species are not a conjugate acid-base pair because they vary by nitrogen rather than a proton (H鈦). We can write the correct conjugate acid-base pair for each species as follows: For HClO: Acid - HClO, Conjugate Base - ClO鈦 For HClO鈧: Acid - HClO鈧, Conjugate Base - ClO鈧傗伝 c. H鈧働O鈧, PO鈧劼斥伝
03

Analyzing the pair

H鈧働O鈧 is an acid that can donate a proton (H鈦) to form H鈧侾O鈧勨伝. Since the given ion PO鈧劼斥伝 is not formed by the loss of a single proton (H鈦) from H鈧働O鈧, these are not a conjugate pair. The correct conjugate pairs are as follows: For H鈧働O鈧: Acid - H鈧働O鈧, Conjugate Base - H鈧侾O鈧勨伝 For PO鈧劼斥伝: Acid - HPO鈧劼测伝, Conjugate Base - PO鈧劼斥伝 d. H鈧侰O鈧, CO鈧兟测伝
04

Analyzing the pair

Here, H鈧侰O鈧 is an acid that can donate a proton (H鈦) to form HCO鈧冣伝. Since the given ion, CO鈧兟测伝, is formed by the loss of two protons (H鈦) from H鈧侰O鈧, these are not a conjugate acid-base pair. The correct conjugate pairs are as follows: For H鈧侰O鈧: Acid - H鈧侰O鈧, Conjugate Base - HCO鈧冣伝 For CO鈧兟测伝: Acid - HCO鈧冣伝, Conjugate Base - CO鈧兟测伝

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Acid-Base Chemistry
Acid-base chemistry is a fundamental concept that encompasses the reactions between acids and bases. In essence, it involves the exchange of protons (hydrogen ions, H鈦) from acids to bases. Acids are substances that can donate protons, whereas bases are substances that can accept them. When an acid loses a proton, it becomes a base, known as the conjugate base of the original acid. Conversely, when a base gains a proton, it becomes an acid, called the conjugate acid of the original base.

Understanding the behavior of acids and bases is crucial for a variety of chemical processes, ranging from industrial applications to biological systems. Even the water we drink is subjected to acid-base interactions, which affect its pH level and, consequently, its suitability for consumption. The identification of conjugate acid-base pairs, as seen in the exercise provided, is a key skill in mastering acid-base chemistry.
Proton Transfer Reactions
Proton transfer reactions are at the heart of acid-base chemistry, characterized by the movement of protons from one substance to another. These reactions are also known as 'proton hopping' and are a type of chemical reaction that involves the transfer of a proton from an acid to a base. A classic example is the reaction between hydrogen chloride (HCl) and water, where HCl donates a proton to water, forming hydronium ions (H鈧僌鈦) and chloride ions (Cl鈦).

In the context of the exercise, we analyzed various pairs to determine if they were conjugate acid-base pairs. This involved checking whether the species differ by exactly one proton. Not all given pairs met this criterion, highlighting the necessity to discern subtle differences between molecular structures to accurately predict and understand proton transfer reactions.
Br酶nsted-Lowry Theory
The Br酶nsted-Lowry theory is a widely accepted theory of acids and bases formulated by Johannes Br酶nsted and Thomas Lowry. This theory defines an acid as a proton donor and a base as a proton acceptor. It expands upon previous theories by accounting for the role of proton transfer in acid-base reactions and provides a broader perspective compared to other theories such as the Arrhenius theory, which limits acids and bases to aqueous solutions.

According to the Br酶nsted-Lowry theory, the chemical reaction between an acid and base results in the formation of a conjugate acid-base pair, which ties into the exercise where the concept was practically applied. It emphasized the importance of recognizing conjugate pairs and showed that not all species that differ in one atom, or even one proton, necessarily constitute a conjugate acid-base pair, reinforcing the need to closely examine the molecular changes that occur during proton transfer.

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