The compound sodium thiosulfate pentahydrate, \(\mathrm{Na}_{2} \mathrm{S}_{2}
\mathrm{O}_{3} \cdot 5 \mathrm{H}_{2} \mathrm{O},\) is important commercially
to the
photography business as "hypo," because it has the ability to dissolve
unreacted silver salts from photographic film during development. Sodium
thiosulfate pentahydrate can be produced by boiling elemental sulfur in an
aqueous solution of sodium sulfite.
$$\mathrm{S}_{8}(s)+\mathrm{Na}_{2} \mathrm{SO}_{3}(a q)+\mathrm{H}_{2}
\mathrm{O}(l) \rightarrow \mathrm{Na}_{2} \mathrm{S}_{2} \mathrm{O}_{3} \cdot
5 \mathrm{H}_{2} \mathrm{O}(s)$$ (unbalanced)
What is the theoretical yield of sodium thiosulfate pentahydrate when \(3.25
\mathrm{g}\) of sulfur is boiled with 13.1 g of sodium sulfite? Sodium
thiosulfate pentahydrate is very soluble in water. What is the percent yield
of the synthesis if a student doing this experiment is able to isolate
(collect) only \(5.26 \mathrm{g}\) of the product?