Chapter 17: Problem 82
Corrosion of a metal represents its __________ by species present in the atmosphere.
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Chapter 17: Problem 82
Corrosion of a metal represents its __________ by species present in the atmosphere.
These are the key concepts you need to understand to accurately answer the question.
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Balance each of the following oxidation-reduction reactions, which take place in acidic solution. a. \(\mathrm{MnO}_{4}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}_{2}(a q) \rightarrow \mathrm{Mn}^{2+}(a q)+\mathrm{O}_{2}(g)\) b. \(\operatorname{Br} \mathrm{O}_{3}^{-}(a q)+\mathrm{Cu}^{+}(a q) \rightarrow \mathrm{Br}^{-}(a q)+\mathrm{Cu}^{2+}(a q)\) c. \(\mathrm{HNO}_{2}(a q)+\mathrm{I}^{-}(a q) \rightarrow \mathrm{NO}(g)+\mathrm{I}_{2}(a q)\)
What is the oxidation state of the atoms in an uncombined element? Does it depend on whether the element occurs as a diatomic molecule \(\left(\mathrm{O}_{2}, \mathrm{N}_{2}\right)\) or as a larger molecule \(\left(\mathrm{P}_{4}, \mathrm{S}_{8}\right) ?\)
Explain why, although it is not an ionic compound, we still assign oxygen an oxidation state of -2 in water, \(\mathrm{H}_{2} \mathrm{O}\). Give an example of a compound in which oxygen is not in the -2 oxidation state.
Balance each of the following half-reactions, which take place in acidic solution. a. \(\mathrm{NO}_{3}^{-}(a q) \rightarrow \mathrm{NO}(g)\) b. \(\mathrm{NO}_{3}^{-}(a q) \rightarrow \mathrm{NO}_{2}(g)\) c. \(\mathrm{H}_{2} \mathrm{SO}_{4}(l) \rightarrow \mathrm{SO}_{2}(g)\) d. \(\mathrm{H}_{2} \mathrm{O}_{2}(a q) \rightarrow \mathrm{H}_{2} \mathrm{O}(l)\)
In each of the following reactions, identify which element is oxidized and which is reduced by assigning oxidation states. a. \(2 \mathrm{Cu}(s)+\mathrm{S}(s) \rightarrow \mathrm{Cu}_{2} \mathrm{S}(s)\) b. \(2 \mathrm{Cu}_{2} \mathrm{O}(s)+\mathrm{O}_{2}(g) \rightarrow 4 \mathrm{CuO}(s)\) c. \(4 \mathrm{B}(s)+3 \mathrm{O}_{2}(g) \rightarrow 2 \mathrm{B}_{2} \mathrm{O}_{3}(s)\) d. \(6 \mathrm{Na}(s)+\mathrm{N}_{2}(g) \rightarrow 2 \mathrm{Na}_{3} \mathrm{N}(s)\)
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