Chapter 16: Problem 74
A ____ speeds up a reaction without being consumed.
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Chapter 16: Problem 74
A ____ speeds up a reaction without being consumed.
These are the key concepts you need to understand to accurately answer the question.
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The three common silver halides (AgCl, AgBr, and AgI) are all sparingly soluble salts. Given the values for \(K_{\mathrm{sp}}\) for these salts below, calculate the concentration of silver ion, in \(\mathrm{mol} / \mathrm{L},\) in a saturated solution of each salt. $$ \text {Silver Halide } \quad \quad\quad\quad \text {\(K_{\mathrm{sp}}\)} $$ $$ \text {\(\mathrm{AgCl}\) } \quad \quad \text {\(1.8 \times 10^{-10}\)} $$ $$ \text {\(\mathrm{AgBr}\) } \quad \quad \text {\(5.0 \times 10^{-13}\)} $$ $$ \text {\(\mathrm{Agl}\) } \quad \quad \text {\(8.3 \times 10^{-17}\)} $$
Gaseous phosphorus pentachloride decomposes according to the reaction $$\mathrm{PCl}_{5}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)$$ The equilibrium system was analyzed at a particular temperature, and the concentrations of the substances present were determined to be \(\left[\mathrm{PCl}_{5}\right]=\) \(1.1 \times 10^{-2} \mathrm{M},\left[\mathrm{PCl}_{3}\right]=0.325 \mathrm{M},\) and \(\left[\mathrm{Cl}_{2}\right]=3.9 \times\) \(10^{-3} M .\) Calculate the value of \(K\) for the reaction.
Write the equilibrium expression for each of the following reactions. a. \(\mathrm{NO}(g)+\mathrm{O}_{3}(g) \rightleftharpoons \mathrm{NO}_{2}(g)+\mathrm{O}_{2}(g)\) b. \(\mathrm{SO}_{2}(g)+\mathrm{NO}_{2}(g) \rightleftharpoons \mathrm{SO}_{3}(g)+\mathrm{NO}(g)\) c. \(2 \mathrm{Cl}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons 4 \mathrm{HCl}(g)+\mathrm{O}_{2}(g)\)
The equilibrium constant for the reaction $$2 \mathrm{NOCl}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Cl}_{2}(g)$$ has the value \(9.2 \times 10^{-6}\) at a particular temperature. The system is analyzed at equilibrium, and it is found that the concentrations of \(\mathrm{NOCl}(g)\) and \(\mathrm{NO}(g)\) are \(0.44 \mathrm{M}\) and \(1.5 \times 10^{-3} \mathrm{M},\) respectively. What is the concentration of \(\mathrm{Cl}_{2}(g)\) in the equilibrium system under these conditions?
How does an increase in temperature result in an increase in the number of successful collisions between reactant molecules? What does an increase in temperature mean on a molecular basis?
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