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Which component of a buffered solution consumes added strong base? Using your example from Question 60, show how this component would react with added NaOH.

Short Answer

Expert verified
In a buffered solution, the weak acid component consumes the added strong base. Considering a buffer containing acetic acid (CH鈧僀OOH) and its conjugate base, acetate ion (CH鈧僀OO鈦), the reaction with added NaOH can be written as: \( CH鈧僀OOH + NaOH \rightarrow CH鈧僀OO鈦 + H鈧侽 + Na^+ \) The acetic acid donates a proton (H鈦) to the hydroxide ion (OH鈦) from NaOH, neutralizing the strong base and maintaining the pH relatively stable.

Step by step solution

01

1. Understand the components of the buffered solution

A buffered solution typically consists of a weak acid and its conjugate base or a weak base and its conjugate acid. These components work together to maintain the pH of the solution relatively stable when small amounts of an acid or a base are added.
02

2. Identify the component that consumes the added strong base

When a strong base is added to a buffered solution, it will react with the weak acid component present in the buffer. In this reaction, the weak acid will donate a proton (H+) to the strong base, forming its conjugate base and neutralizing the added base.
03

3. Recall example from question 60

Unfortunately, we do not have the example from question 60. However, to demonstrate the concept, let's consider a buffered solution containing acetic acid (CH鈧僀OOH) as the weak acid and its conjugate base, the acetate ion (CH鈧僀OO鈦). We will show how this buffer system reacts with added NaOH.
04

4. Write the reaction between the weak acid and the strong base

The reaction between the weak acid (acetic acid, CH鈧僀OOH) and the strong base (NaOH) will be as follows: \( CH鈧僀OOH + NaOH \rightarrow CH鈧僀OO鈦 + H鈧侽 + Na^+ \) When NaOH is added to the buffered solution, the acetic acid (CH鈧僀OOH) donates a proton (H鈦) to the hydroxide ion (OH鈦) from NaOH. As a result, the acetate ion (CH鈧僀OO鈦) is formed, water (H鈧侽), and a sodium ion (Na鈦). This reaction neutralizes the added strong base (NaOH) and helps maintain the pH of the solution relatively stable.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Weak Acid
A weak acid is an acid that does not completely dissociate in water. This means that only a small fraction of the weak acid molecules break apart into ions when dissolved in water. Because of this partial dissociation, weak acids only partly donate hydrogen ions (H鈦) to the solution. Common examples of weak acids include acetic acid (CH鈧僀OOH) and citric acid.

Weak acids are crucial in buffered solutions because they can react with added bases, like NaOH, to help maintain pH stability. By releasing protons (H鈦) when needed, a weak acid helps neutralize strong bases, converting them into water and reducing disruptions in the solution's pH.

In practical terms, imagine making lemonade with just a hint of lemon: you still taste the sourness, but it's subtle rather than overwhelming. That's somewhat like how weak acids behave in solutions鈥攑roviding acidity, but not in an intense way.
Conjugate Base
The conjugate base is what remains after a weak acid donates a hydrogen ion (H鈦). In the case of acetic acid, once the acid donates an H鈦 ion, it becomes the acetate ion (CH鈧僀OO鈦), which is its conjugate base.

In a buffered solution, the role of the conjugate base is to work with the weak acid to handle any added acids. While the weak acid in the buffer tackles added bases, the conjugate base can mop up extra hydrogen ions that might be added, maintaining balance in the solution.

This team effort between a weak acid and its conjugate base is essential for keeping the pH stable. Their cooperative nature helps the buffered solution resist changes caused by small amounts of either strong acids or bases.
Reaction with Strong Base
When a strong base, such as NaOH, is introduced to a buffered solution, it primarily interacts with the weak acid present. The weak acid, like acetic acid (CH鈧僀OOH), donates an H鈦 ion to the hydroxide ion (OH鈦) from the strong base. This interaction creates water (H鈧侽) and forms the conjugate base, acetate ion (CH鈧僀OO鈦), from the former weak acid.

This reaction can be summarized by the equation:

\( CH鈧僀OOH + NaOH \rightarrow CH鈧僀OO鈦 + H鈧侽 + Na^+ \)

The hydrogen ion neutralizes the hydroxide ion effectively, preventing a significant rise in the pH level. This is the true power of a buffer鈥攁llowing the addition of strong bases like NaOH without drastic changes in pH levels.
pH Stability
pH stability is a hallmark of buffered solutions. It's the ability to resist significant changes in pH when small amounts of acid or base are added. This stability is crucial in various natural and industrial processes where maintaining a specific pH range is essential.

Buffered solutions like the acetic acid-acetate buffer provide this stability by having both a weak acid and its conjugate base. When external substances like strong bases are introduced, they are neutralized without significant shifts in pH level.

In biological systems, for example, maintaining pH stability is vital. Blood, with a pH around 7.4, is a buffered solution that keeps the body's internal environment stable, enabling enzymes and biochemical reactions to proceed optimally. Similarly, in industrial processes, pH stability ensures that reactions occur as expected without unwanted side reactions.

Overall, the presence of both components鈥攚eak acid and conjugate base鈥攁llows buffered solutions to act as effective pH protectors.

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