Chapter 12: Problem 47
Show how Boyle's gas law can be derived from the ideal gas law.
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Chapter 12: Problem 47
Show how Boyle's gas law can be derived from the ideal gas law.
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What volume does \(0.103 \mathrm{mol}\) of \(\mathrm{N}_{2}\) gas occupy at a temperature of \(27^{\circ} \mathrm{C}\) and a pressure of \(784 \mathrm{mm} \mathrm{Hg} ?\)
As we noted in Example \(12.6,\) gas volume was formerly used as a way to measure temperature by applying Charles's law. Suppose a sample in a gas thermometer has a volume of \(135 \mathrm{mL}\) at \(11^{\circ} \mathrm{C}\). Indicate what temperature would correspond to each of the following volumes, assuming that the pressure remains constant: \(113 \mathrm{mL}, 142 \mathrm{mL}, 155 \mathrm{mL}, 127 \mathrm{mL}.\)
When ammonium carbonate is heated, three gases are produced by its decomposition. $$ \left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}_{3}(s) \rightarrow 2 \mathrm{NH}_{3}(g)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ What total volume of gas is produced, measured at \(453^{\circ} \mathrm{C}\) and 1.04 atm, if \(52.0 \mathrm{g}\) of ammonium carbonate is heated?
Suppose two 200.0 -L tanks are to be filled separately with the gases helium and hydrogen. What mass of each gas is needed to produce a pressure of 135 atm in its respective tank at \(24^{\circ} \mathrm{C} ?\)
Given each of the following sets of values for three of the gas variables, calculate the unknown quantity. a. \(P=7.74 \times 10^{3} \mathrm{Pa} ; V=12.2 \mathrm{mL} ; n=? \mathrm{mol} ; T=\) \(298 \mathrm{K}\) b. \(P=? \mathrm{mm} \mathrm{Hg} ; V=43.0 \mathrm{mL} ; n=0.421 \mathrm{mol} ; T=\) \(223 \mathrm{K}\) c. \(\bar{P}=455 \mathrm{mm}\) Hg; \(V=? \mathrm{mL} ; n=4.4 \times 10^{-2} \mathrm{mol}\) \(T=331^{\circ} \mathrm{C}\)
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