Chapter 8: Problem 10
From the element's position on the periodic table, predict the electron configuration of each atom. a) \(\mathrm{Fe}\) b) \(\mathrm{Ba}\)
Short Answer
Expert verified
Fe: [Ar] 4s虏 3d鈦; Ba: [Xe] 6s虏.
Step by step solution
01
Understanding Element Categories
Identify the element Fe (iron) as a transition metal located in period 4 and group 8, and Ba (barium) as an alkaline earth metal located in period 6 and group 2 of the periodic table.
02
Electron Configuration for Fe
Iron ( ext{Fe}) is located in period 4. We begin filling the electron configuration in the 1s, 2s, 2p, 3s, 3p, 4s, then 3d subshell. Iron has 26 electrons.
So, the full electron configuration will be:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鈦.
We can simplify this using the nearest noble gas: [Ar] 4s虏 3d鈦.
03
Electron Configuration for Ba
Barium ( ext{Ba}) is located in period 6. We fill the electron configuration starting from 1s to 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, ending in 6s. Barium has 56 electrons.
The full electron configuration is:
1s虏 2s虏 2p鈦 3s虏 3p鈦 4s虏 3d鹿鈦 4p鈦 5s虏 4d鹿鈦 5p鈦 6s虏.
We can simplify this using the nearest noble gas: [Xe] 6s虏.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Periodic Table
The periodic table is an organized chart that displays all known elements by increasing atomic number, which correlates to the number of protons in an element's nucleus. This layout not only showcases the elements themselves but also reveals periodic trends in their properties.
By looking at its periods (rows) and groups (columns), we can understand how elements tend to behave and predict how they interact. Elements are arranged in periods which are horizontal rows, reflecting increasing energy levels as one moves across a period. Groups are vertical columns where elements have similar properties and electron configurations.
When considering electron configurations, the position of an element on the periodic table provides valuable insights. Each element鈥檚 location helps us predict its electron configuration, as elements in the same group often share the same outer electron configuration (valence electron structure). This shared structure explains their similar chemical properties. Group numbers can hint at the number of valence electrons an element might possess.
By looking at its periods (rows) and groups (columns), we can understand how elements tend to behave and predict how they interact. Elements are arranged in periods which are horizontal rows, reflecting increasing energy levels as one moves across a period. Groups are vertical columns where elements have similar properties and electron configurations.
When considering electron configurations, the position of an element on the periodic table provides valuable insights. Each element鈥檚 location helps us predict its electron configuration, as elements in the same group often share the same outer electron configuration (valence electron structure). This shared structure explains their similar chemical properties. Group numbers can hint at the number of valence electrons an element might possess.
Transition Metals
Transition metals are a special group of elements found in the middle of the periodic table, specifically in groups 3 through 12. These metals, like iron (Fe), are distinguished by their ability to form various oxidation states and colorful compounds.
A hallmark of transition metals is their partially filled d orbitals. Their electron configurations typically include an extended filling sequence of the d subshell (e.g., 3d, 4d, 5d) after the initial s subshell has been filled. For instance, iron's electronic configuration can be written as \[ \text{[Ar]} 4s^2 3d^6 . \] This notation indicates that after filling up to argon, we proceed to add electrons to 4s, then 3d. Transition metals often form complex ions by donating electrons from these d orbitals, which explains their dynamic behavior in various chemical reactions.
In addition, they exhibit high melting points, magnetic properties, and good conductivity which are leveraged in many industrial applications. They play a vital role in biological systems as well, contributing to oxygen transport, electron transfer, and catalysis.
A hallmark of transition metals is their partially filled d orbitals. Their electron configurations typically include an extended filling sequence of the d subshell (e.g., 3d, 4d, 5d) after the initial s subshell has been filled. For instance, iron's electronic configuration can be written as \[ \text{[Ar]} 4s^2 3d^6 . \] This notation indicates that after filling up to argon, we proceed to add electrons to 4s, then 3d. Transition metals often form complex ions by donating electrons from these d orbitals, which explains their dynamic behavior in various chemical reactions.
In addition, they exhibit high melting points, magnetic properties, and good conductivity which are leveraged in many industrial applications. They play a vital role in biological systems as well, contributing to oxygen transport, electron transfer, and catalysis.
Alkaline Earth Metals
Alkaline earth metals compose group 2 of the periodic table and include elements like barium (Ba). These elements are recognized for having two electrons in their outermost s subshell, giving them the general electron configuration of \[ \text{[Noble gas]} ns^2 . \]
They are known for being quite reactive, though not as much as their group 1 counterparts, the alkali metals. The reactivity of alkaline earth metals increases down the group as the outer electrons are progressively farther from the nucleus, making them easier to lose. Such properties make them excellent reducing agents.
Alkaline earth metals tend to form compounds that are less soluble compared to those of Group 1, and they usually form ionic compounds, resulting in the formation of stable crystal lattices. For example, barium forms insoluble sulfates that find use in various industries, including papermaking and oil drilling. Additionally, these metals frequently see use in fireworks, batteries, and biochemical research due to their unique properties.
They are known for being quite reactive, though not as much as their group 1 counterparts, the alkali metals. The reactivity of alkaline earth metals increases down the group as the outer electrons are progressively farther from the nucleus, making them easier to lose. Such properties make them excellent reducing agents.
Alkaline earth metals tend to form compounds that are less soluble compared to those of Group 1, and they usually form ionic compounds, resulting in the formation of stable crystal lattices. For example, barium forms insoluble sulfates that find use in various industries, including papermaking and oil drilling. Additionally, these metals frequently see use in fireworks, batteries, and biochemical research due to their unique properties.