Chapter 4: Problem 16
Write the complete and net ionic equations for the neutralization reaction between \(\mathrm{HClO}_{3}(\mathrm{aq})\) and \(\mathrm{Zn}(\mathrm{OH}) 2(\mathrm{~s})\) using the hydronium ion in place of \(\mathrm{H}^{+}\). Assume the salt is soluble. What difference does it make when using the hydronium ion?
Short Answer
Step by step solution
Write the Balanced Chemical Equation
Write Complete Ionic Equation
Identify Spectator Ions
Write Net Ionic Equation
Observations on Using Hydronium Ion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Neutralization Reaction
Neutralization reactions are commonly seen in everyday processes, such as the use of antacids to neutralize stomach acid.
Here’s a simple breakdown of how they work:
- Acids, like chloric acid (\( ext{HClO}_3\)), release hydrogen ions (\( ext{H}^+\)) in solution.
- Bases, like zinc hydroxide (\( ext{Zn(OH)}_2\)), release hydroxide ions (\( ext{OH}^-\)).
- These ions combine to form water: \(2 ext{H}^+ + 2 ext{OH}^- ightarrow 2 ext{H}_2 ext{O}\)
Hydronium Ion
\[ ext{H}^+ + ext{H}_2 ext{O} ightarrow ext{H}_3 ext{O}^+\]The formation of hydronium ions is a more accurate representation of the acid’s presence in aqueous solutions. This is because free hydrogen ions do not exist independently for long in water.
Using hydronium ions instead of hydrogen ions, as seen in our equation, gives a more precise picture of the acidic components’ interaction.
Additionally, accounting for hydronium ions helps chemists better understand the strength and concentration of an acid in a solution, making this approach valuable in predicting reactions involving acids.
Spectator Ions
In our reaction between chloric acid and zinc hydroxide, the \( ext{ClO}_3^-\) ions function as spectator ions. They appear unchanged on both sides of the complete ionic equation:
\[ ext{H}_3 ext{O}^+( ext{aq}) + ext{ClO}_3^-( ext{aq}) + ext{Zn(OH)}_2( ext{s}) ightarrow ext{Zn}^{2+}( ext{aq}) + 2 ext{ClO}_3^-( ext{aq}) + 2 ext{H}_2 ext{O}( ext{l})\]
Since spectator ions do not affect the net result of the reaction, they are removed when writing net ionic equations.
This simplification allows us to focus on the active components of the reaction, yielding a clearer understanding of the true chemical processes occurring.
Chemical Equations
The steps involved in writing a chemical equation generally include:
- Identifying the reactants and products.
- Determining the physical states (solid, liquid, gas, or aqueous).
- Balancing the number of atoms and charges on both sides.
Writing complete and net ionic equations further break this down by focusing on the ions participating in the reaction while omitting the spectator ions. This progression aids in understanding the specifics of how substances interact in chemically reactive ways.