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The label on a sparkling cider says it contains \(22.0 \mathrm{g}\) glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right), 190 . \mathrm{mg} \mathrm{K}^{+},\) and \(4.00 \mathrm{mg} \mathrm{Na}^{+}\) per serving of \(240 .\) mL of cider. Calculate the molarities of these ingredients in the sparkling cider.

Short Answer

Expert verified
The molarities are 0.508 M (glucose), 0.02025 M (\(\mathrm{K}^{+}\)), and 0.000725 M (\(\mathrm{Na}^{+}\)).

Step by step solution

01

Calculate the moles of glucose

We use the molar mass of glucose, which is \(C_{6}H_{12}O_{6}\). The molar mass of glucose is calculated as: \((6\times12.01) + (12\times1.01) + (6\times16.00) = 180.16\; \text{g/mol}\). Now, moles of glucose: \(\frac{22.0 \; \text{g}}{180.16 \; \text{g/mol}} = 0.122 \; \text{mol}\).
02

Calculate the molarity of glucose

The formula for molarity is \(M = \frac{\text{moles of solute}}{\text{liters of solution}}\). The volume of the cider is 240 mL, which is \(0.240 \; L\). Therefore, molarity \(M = \frac{0.122 \; \text{mol}}{0.240 \; \text{L}} = 0.508 \; \text{M}\).
03

Calculate the moles of potassium ions

The mass of \(\mathrm{K}^{+}\) is \(190 \; \text{mg} = 0.190 \; \text{g}\). The molar mass of \(\mathrm{K}^{+}\) is \(39.10 \; \text{g/mol}\). So, moles of \(\mathrm{K}^{+}\): \(\frac{0.190 \; \text{g}}{39.10 \; \text{g/mol}} = 0.00486 \; \text{mol}\).
04

Calculate the molarity of potassium ions

The volume of the solution is 240 mL or 0.240 L. Molarity of \(\mathrm{K}^{+}\): \(M = \frac{0.00486 \; \text{mol}}{0.240 \; \text{L}} = 0.02025 \; \text{M}\).
05

Calculate the moles of sodium ions

The mass of \(\mathrm{Na}^{+}\) is \(4.00 \; \text{mg} = 0.00400 \; \text{g}\). The molar mass of \(\mathrm{Na}^{+}\) is \(23.00 \; \text{g/mol}\). So, moles of \(\mathrm{Na}^{+}\): \(\frac{0.00400 \; \text{g}}{23.00 \; \text{g/mol}} = 0.000174 \; \text{mol}\).
06

Calculate the molarity of sodium ions

With a solution volume of 0.240 L, molarity of \(\mathrm{Na}^{+}\): \(M = \frac{0.000174 \; \text{mol}}{0.240 \; \text{L}} = 0.000725 \; \text{M}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding the Molarity of Glucose
When you hear the word 'molarity,' it refers to the concentration of a solution. Specifically, it measures the number of moles of solute per liter of solution. In this context, we need to calculate the molarity of glucose in sparkling cider.

First, identify the amount of glucose provided, which is 22.0 grams. To find how many moles are present, we use the molecular weight. Glucose has the formula \(C_{6}H_{12}O_{6}\), and its molar mass is calculated as follows:

\[ (6 \times 12.01) + (12 \times 1.01) + (6 \times 16.00) = 180.16 \; \text{g/mol} \]

Thus, to determine the moles, we divide the grams of glucose by its molar mass:
\[ \text{Moles of glucose} = \frac{22.0 \; \text{g}}{180.16 \; \text{g/mol}} = 0.122 \; \text{mol} \]

Then, convert the volume of the cider from milliliters to liters. Here, 240 mL is equivalent to 0.240 L. Finally, apply the formula for molarity:

\[ M = \frac{\text{moles of solute}}{\text{liters of solution}} = \frac{0.122 \; \text{mol}}{0.240 \; \text{L}} = 0.508 \; \text{M} \]

This process allows you to understand the concentration of glucose in each serving, representing how densely glucose is packed into the cider.
Calculating Potassium Ion Concentration
The concentration of ions, like potassium, in a solution is also expressed in terms of molarity. Let's explore how to compute this for potassium ions in the cider.

Begin with the mass of potassium ions provided: 190 mg, which needs conversion to grams:

\[ 190 \; \text{mg} = 0.190 \; \text{g} \]

The molar mass of potassium ions \(\mathrm{K}^{+}\) is 39.10 g/mol. This allows us to determine the moles of \(\mathrm{K}^{+}\) as follows:

\[ \text{Moles of } \mathrm{K}^{+} = \frac{0.190 \; \text{g}}{39.10 \; \text{g/mol}} = 0.00486 \; \text{mol} \]

Given the volume of cider is 0.240 L, calculate the molarity:

\[ M = \frac{0.00486 \; \text{mol}}{0.240 \; \text{L}} = 0.02025 \; \text{M} \]

This indicates there is 0.02025 moles of \(\mathrm{K}^{+}\) per liter of cider, providing a clear understanding of how potassium ions are distributed in the beverage.
Determining Sodium Ion Concentration
Sodium ion concentration, like that of glucose and potassium, also follows the same principles of molarity. To find this concentration, start by identifying the amount of sodium ions: 4.00 mg.

Convert milligrams to grams:
\[ 4.00 \; \text{mg} = 0.00400 \; \text{g} \]

Next, use the molar mass of sodium ions \(\mathrm{Na}^{+}\), which is 23.00 g/mol. Thus, you can calculate the moles of sodium ions by:

\[ \text{Moles of } \mathrm{Na}^{+} = \frac{0.00400 \; \text{g}}{23.00 \; \text{g/mol}} = 0.000174 \; \text{mol} \]

With the cider's volume in liters also set to 0.240, find the molarity of sodium ions:

\[ M = \frac{0.000174 \; \text{mol}}{0.240 \; \text{L}} = 0.000725 \; \text{M} \]

Through this calculation, you determine that there is a small concentration of sodium ions in the cider, illustrating its presence on a molar scale.

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Most popular questions from this chapter

As noted in Section \(6.8 \mathrm{C}\), the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure ( \(\pi\) ). The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5.4 ), where \(P V=n R T\). Substituting \(\pi\) for pressure and solving for osmotic pressures gives the following equation: \(\pi=\left(\frac{n}{V}\right) R T=M R T,\) where \(M\) is the concentration or molarity of the solution. (a) Determine the osmotic pressure at \(25^{\circ} \mathrm{C}\) of a \(0.0020 M\) sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) solution. (b) Seawater contains \(3.4 \mathrm{g}\) of salts for every liter of solution. Assuming the solute consists entirely of \(\mathrm{NaCl}\) (and complete dissociation of the \(\mathrm{NaCl}\) salt) calculate the osmotic pressure of seawater at \(25^{\circ} \mathrm{C}\) (c) The average osmotic pressure of blood is 7.7 atm at \(25^{\circ} \mathrm{C} .\) What concentration of glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing \(0.150 \mathrm{g}\) of this enzyme in \(210 .\) mL of solution has an osmotic pressure of 0.953 torr at \(25^{\circ} \mathrm{C}\). What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained \(3.50 \mathrm{mg}\) of protein dissolved in sufficient water to form \(5.00 \mathrm{mL}\) of solution. The osmotic pressure of the solution at \(25^{\circ} \mathrm{C}\) was found to be 1.54 torr. Calculate the molar mass of the protein.

Ethanol is very soluble in water. Describe how water dissolves ethanol.

Table 6.2 shows no examples of a gas-in-gas colloidal system. Considering the definition of a colloid, explain why.

List the following aqueous solutions in order of decreasing freezing point: \(0.040 M\) glycerin \(\left(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}_{3}\right)\) \(0.025 M \mathrm{NaBr},\) and \(0.015 \mathrm{M} \mathrm{Al}\left(\mathrm{NO}_{3}\right)_{3}\). Assume complete dissociation of any salts.

What is the osmolarity of a Pedialyte solution containing \(45 \mathrm{mEq} / \mathrm{L} \mathrm{Na}^{+}, 20 . \mathrm{mEq} / \mathrm{L} \mathrm{K}^{+}, 35 \mathrm{mEq} / \mathrm{L} \mathrm{Cl}^{-}\) \(30 . \mathrm{mEq} / \mathrm{L} \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{O}_{7}^{3-}(\text { citrate }),\) and \(25 \mathrm{g} / \mathrm{L} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) (glucose)?

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